Organic Chemistry: A Guided Inquiry
2nd Edition
ISBN: 9780618974122
Author: Andrei Straumanis
Publisher: Cengage Learning
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Chapter 4, Problem 29CTQ
Interpretation Introduction
Interpretation: Whether below reactions are endothermic or exothermic should be determined.
Concept introduction:
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Question 5 of 8
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Calculate AH° for the reaction using the given bond dissociation energies.
CH₂(g) + 2O₂(g) → CO₂(g) + 2 H₂O(g)
Bond AH° (kJ/mol)
O-O
H-O
C-H
C=O
O=O
C-O
ΔΗ° =
142
459
411
799
498
358
kJ/mol
This reaction is
exothermic.
endothermic.
Jorge is trying to classify the reaction represented by
the graph below and calculate the change in energy, AH
for it.
250
200-
..
PE
150
(KJ)
....
100
...
50
Reaction pathway
He claims that the AH will be -100kJ and the reaction is
exothermic. Is his claim correct? If not, find the errors
and fix them to give the correct answer. Make sure to
show ALL work and give explanations.
40 kJ
Reactants
Na
Activation Energy
CI
30 kJ
Products
Na
CI
H
10 kJ
Reaction Progress
Na
H CI
Potential Energy [kJ]
Chapter 4 Solutions
Organic Chemistry: A Guided Inquiry
Ch. 4 - Prob. 1CTQCh. 4 - Figure 4.1 is a cartoon depiction of liquid water...Ch. 4 - Prob. 3CTQCh. 4 - Prob. 4CTQCh. 4 - In HF , neither H nor F holds a full formal charge...Ch. 4 - Prob. 6CTQCh. 4 - Prob. 7CTQCh. 4 - Prob. 8CTQCh. 4 - Within any one section of Table 4.2, boiling...Ch. 4 - Prob. 10CTQ
Ch. 4 - Prob. 11CTQCh. 4 - Prob. 12CTQCh. 4 - Prob. 13CTQCh. 4 - Prob. 14CTQCh. 4 - Prob. 15CTQCh. 4 - Prob. 16CTQCh. 4 - Prob. 17CTQCh. 4 - Prob. 18CTQCh. 4 - Prob. 19CTQCh. 4 - Prob. 20CTQCh. 4 - Prob. 21CTQCh. 4 - Prob. 22CTQCh. 4 - (E) Label each of the following as strong acid,...Ch. 4 - Prob. 24CTQCh. 4 - Draw the structure of the conjugate base of water....Ch. 4 - Does Cl have a conjugate acid? If so, what is it?...Ch. 4 - Draw the conjugate base of CH4 (methane).Ch. 4 - For the previous four questions, label each...Ch. 4 - Prob. 29CTQCh. 4 - According to the conventions above, what is the...Ch. 4 - Draw an arrow on Figure 4.13 representing Hrxn4 ....Ch. 4 - Prob. 32CTQCh. 4 - Add a + or above each curved arrow in Figure 4.11...Ch. 4 - Prob. 34CTQCh. 4 - Prob. 35CTQCh. 4 - Prob. 36CTQCh. 4 - Prob. 37CTQCh. 4 - Prob. 38CTQCh. 4 - Prob. 39CTQCh. 4 - Prob. 40CTQCh. 4 - Prob. 41CTQCh. 4 - Prob. 42CTQCh. 4 - Prob. 43CTQCh. 4 - Prob. 44CTQCh. 4 - Prob. 45CTQCh. 4 - Prob. 46CTQCh. 4 - For NH3 (ammonia) and H2O (water)... a. Use curved...Ch. 4 - Prob. 48CTQCh. 4 - Prob. 49CTQCh. 4 - Prob. 50CTQCh. 4 - Prob. 51CTQCh. 4 - Prob. 52CTQCh. 4 - Prob. 53CTQCh. 4 - Prob. 1ECh. 4 - Prob. 2ECh. 4 - Prob. 3ECh. 4 - Prob. 4ECh. 4 - Prob. 5ECh. 4 - Prob. 6ECh. 4 - Prob. 7ECh. 4 - Prob. 8ECh. 4 - Propanal (bp 48°C) and propanol (bp 97°C), both...Ch. 4 - Rank the following molecules from lowest to...Ch. 4 - Prob. 12ECh. 4 - For each molecule below, draw the conjugate acid...Ch. 4 - For each structure you drew in the answer to the...Ch. 4 - Mark each of the following statements True or...Ch. 4 - Organic chemistry is a bit like cooking. Later in...Ch. 4 - Prob. 17ECh. 4 - Prob. 18ECh. 4 - Are endothermic reactions favorable or...Ch. 4 - Prob. 20ECh. 4 - Is bond formation endothermic or exothermic? Write...Ch. 4 - Summarize the relationship between pKa and acid...Ch. 4 - Summarize the relationship between pKa and base...Ch. 4 - Prob. 25ECh. 4 - Consider the following bases: a. For each base...Ch. 4 - Prob. 27ECh. 4 - The following are equivalent ways of asking about...Ch. 4 - Prob. 29E
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- The H0 and S0 for the reaction N2O4 N2 + 2O2?arrow_forwardD. H20 (s) –> H20 (I) AHo = 6.01kJ/mol| 1. This reaction depicts the 2. Is this reaction endothermic or exothermic? 3. Is this reaction reversible or irreversible? (process) of (product).arrow_forward(c) The energy of the reactants is shown on the following energy diagram. On the right side of the energy diagram, draw a horizontal line segment to indicate the energy of the products. Draw a vertical double-headed arrow (1) on the graph that corresponds to the value of AH for the reaction. CH4 + F2 Reaction Progress Energyarrow_forward
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- 1. Fill in the boxes below with the correct reagent, reactant or product (5 (а) OH (b) 1. (CH),СHMgBr 2. H,0 ÓH (c) 1. L¡AIH, 2. НО (d) CH;OH H,SO4 (e) 1. 2 (CH3),CHMgBr, 2. H,0 ÓH (f) 1. LIAIH, 2. H,0 HO,arrow_forwardThis reaction is exothermic. Select one: True Falsearrow_forwardenergy (J) A B Iarrow_forward
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