Physical Chemistry
2nd Edition
ISBN: 9781133958437
Author: Ball, David W. (david Warren), BAER, Tomas
Publisher: Wadsworth Cengage Learning,
expand_more
expand_more
format_list_bulleted
Textbook Question
Chapter 20, Problem 20.55E
For what values of time,
Expert Solution & Answer
Want to see the full answer?
Check out a sample textbook solutionStudents have asked these similar questions
The radioactive isotope carbon-14 is present in small quantities in all life forms, and it is
constantly replenished until the organism dies, after which it decays to stable carbon-12 at
a rate proportional to the amount of carbon-14 present, with a half-life of 5594 years.
Suppose C'(t) is the amount of carbon-14 present at time t.
(a) Find the value of the constant k in the differential equation C'=-kC.
k
=
(b) In 1988 three teams of scientists found that the Shroud of Turin, which was reputed to
be the burial cloth of Jesus, contained about 91 percent of the amount of carbon-14
contained in freshly made cloth of the same material[1]. How was old the Shroud of Turin in
1988, according to these data?
Age
=
years
[1]: The New York Times, October 18, 1988.
Suppose a quantity is described by the function y(t) = 30,000e-0.05t, where t is measured in years. Find the half-life of the quantity.
Calculate the fraction of atoms in a sample of argon gas at400 K that has an energy of 10.0 kJ or greater.
Chapter 20 Solutions
Physical Chemistry
Ch. 20 - Prob. 20.1ECh. 20 - The oxidation-reduction reaction between iron...Ch. 20 - The oxidation-reduction reaction between iron...Ch. 20 - The rate of the reaction...Ch. 20 - For a certain reaction between NO and O2, the rate...Ch. 20 - For a reaction between SO2 and Cl2, the rate law...Ch. 20 - Consider the chemical reaction A+B+Cproducts...Ch. 20 - For the chemical reaction...Ch. 20 - Explain how a species might be part of a rate law...Ch. 20 - Refer to Example 20.2 and explain whether any...
Ch. 20 - Rate law experiments dont always give data in the...Ch. 20 - Prob. 20.12ECh. 20 - What must the units on k be for the following rate...Ch. 20 - What must the units on k be for the following rate...Ch. 20 - The reaction 2O33O2 has first-order kinetics and a...Ch. 20 - Digestive processes are first-order processes. The...Ch. 20 - Prob. 20.18ECh. 20 - Derive equation 20.15.Ch. 20 - Prob. 20.20ECh. 20 - To a very good approximation, the cooling of a hot...Ch. 20 - Assume that thermal decomposition of mercuric...Ch. 20 - Prob. 20.23ECh. 20 - Prob. 20.24ECh. 20 - Derive equation 20.22.Ch. 20 - a Write a rate law and an integrated rate law for...Ch. 20 - Derive an expression for the half-life of a a...Ch. 20 - Prob. 20.28ECh. 20 - Rewrite equation 20.27 so that it has the form of...Ch. 20 - One can also define a third-life, t1/3, which is...Ch. 20 - The decomposition of NH3: 2NH3N2+3H2 is a...Ch. 20 - Prob. 20.32ECh. 20 - Prob. 20.33ECh. 20 - When ionic compounds crystallize from a...Ch. 20 - An aqueous reaction that uses the solvent H2O as a...Ch. 20 - The rate law for the reaction...Ch. 20 - If a reaction has the same rate constant, what...Ch. 20 - List at least four experimentally determined...Ch. 20 - Prob. 20.39ECh. 20 - Prob. 20.40ECh. 20 - Prob. 20.41ECh. 20 - Prob. 20.42ECh. 20 - What is the value of the equilibrium constant of a...Ch. 20 - Prob. 20.44ECh. 20 - Prob. 20.45ECh. 20 - Show how equation 20.33 reduces to a simpler form...Ch. 20 - Write expressions like equation 20.37 for a set of...Ch. 20 - Prob. 20.48ECh. 20 - Prob. 20.49ECh. 20 - Prob. 20.50ECh. 20 - Prob. 20.51ECh. 20 - Prob. 20.52ECh. 20 - Prob. 20.53ECh. 20 - Prob. 20.54ECh. 20 - For what values of time, t, will 210Bi and 206Pb...Ch. 20 - Prob. 20.56ECh. 20 - An interesting pair of consecutive reactions...Ch. 20 - Find limiting forms of equation 20.47 for a k1>>k2...Ch. 20 - Prob. 20.59ECh. 20 - Prob. 20.60ECh. 20 - Prob. 20.61ECh. 20 - Prob. 20.62ECh. 20 - At room temperature (22C), the rate constant for...Ch. 20 - Recently, researchers studying the kinetics of...Ch. 20 - A reaction has k=1.771061/(Ms) at 25.0C and an...Ch. 20 - Prob. 20.66ECh. 20 - Prob. 20.67ECh. 20 - Prob. 20.68ECh. 20 - Nitric oxide, NO, is known to break down ozone,...Ch. 20 - a Suggest a mechanism for the bromination of...Ch. 20 - Prob. 20.71ECh. 20 - Prob. 20.72ECh. 20 - Determine a rate law for the chlorination of...Ch. 20 - Determine a rate law for the chlorination of...Ch. 20 - A proposed mechanism for the gas-phase...Ch. 20 - Prob. 20.76ECh. 20 - The nitration of methanol, CH3OH, by nitrous acid...Ch. 20 - Prob. 20.78ECh. 20 - Many gas-phase reactions require some inert body,...Ch. 20 - Prob. 20.80ECh. 20 - Carbonic anhydrase, an enzyme whose substrate is...Ch. 20 - Show that another form of the Michaelis-Menten...Ch. 20 - Prob. 20.83ECh. 20 - Prob. 20.84ECh. 20 - Prob. 20.85ECh. 20 - Prob. 20.86ECh. 20 - Pyrolysis involves heating compounds to break them...Ch. 20 - Prob. 20.88ECh. 20 - Label the elementary processes for the reaction...Ch. 20 - Prob. 20.90ECh. 20 - What are the rate laws of mechanisms 1 and 2 for...Ch. 20 - Estimate G for an elementary process whose rate...Ch. 20 - Prob. 20.93ECh. 20 - Prob. 20.94ECh. 20 - Prob. 20.95ECh. 20 - For the following two reactions H+Cl2HCl+Cl...Ch. 20 - Prob. 20.97ECh. 20 - Prob. 20.98ECh. 20 - Prob. 20.99ECh. 20 - Consider a reaction that has two parallel pathways...Ch. 20 - Consider a set of first-order consecutive...Ch. 20 - Prob. 20.102E
Knowledge Booster
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.Similar questions
- The second law of thermodynamics has been called the arrow of time. Explain why this is so.arrow_forwardConsider the accompanying diagram. Ball A is allowed to fall and strike ball B. Assume that all of ball As energy is transferred to ball B at point I, and that there is no loss of energy to other sources. What is the kinetic energy and the potential energy of ball B at point II? The potential energy is given by PE = mgz, where m is the mass in kilograms, g is the gravitational constant (9.81 m/s2), and z is the distance in meters.arrow_forwardHow long will it take for the intial amount of U-235 to be reduced of this initial amountarrow_forward
- The formation of ammonia (NH) occurs according to the following equation N (9) + 3H (9) - 2N H, (a) The following data was collected over a period of time IHa), M INHl. M 0.4 Time (s) INl. M 0.1000 0.0500 0.035 25 0.25 0.1 50 0,205 О.13 0.1675 0.0225 0.012 75 0.155 100 0,136 0.176 125 0.0008 0.1024 0.1984 150 0.00065 0.10195 0.1987 Use the table to determine the rate of disappearance of hydrogen gas between 100 and 125 s. 7.44 x 10 M/s O 2.38 x 10 M/s о 1.34 х 10Эм/s O 4.20 x 102 M/S O 6.00 x 103 M/sarrow_forward[References) Use the References to access important values if needed for this question. In a study of the gas phase decomposition of dimethyl ether at 500 °C CH;OCH;(g)- →CH4(g) + H2(g) + CO(g) the concentration of CH,OCH, was followed as a function of time. It was found that a graph of In[CH,OCH] versus time in seconds gave a straight line with a slope of -6.28x10s and a y-intercept of -3.50 Based on this plot, the reaction i Đ order in CH,OCH, and the rate constant for the reaction is zero first second Submit Answer Try Another Version 2 item attempts remaining (Previous 12 étv ll MacBook Air 80 DII DD F2 F3 F4 F5 F6 F7 F8 F9 F10 F11 @ #3 $ & * 4 6. 7 8 W E R Y { S G J K く C V ...- ~の * 00 ラ エ Barrow_forwardThe half life for the radioactive decay of potassium-40 to argon-40 is 1.26 × 10 years. Suppose nuclear chemical analysis shows that there is 0.727 mmol of argon-40 for every 1.000 mmol of potassium-40 in a certain sample of rock. Calculate the age of the rock. Round your answer to 2 significant digits. db years Submit Assignment O 2020 McGraw-Hi Education. All Rights Reserved. Terms of Uhe I Pivacy I Accessibility 1113 PM 0 49 12/17/2020 O Type here to search FULL HD 1080 Ecer Del Pg Up Pause Home F11 F12 PrtSc F6 F7 F8 F9 F10 Sa Lk SysRq Break Ins F2 F3 F4 F5 Esc F1 63 z' Nu & Backspace @ # 7 8.arrow_forward
- The half life for the radioactive decay of potassium-40 to argon-40 is 1.26 × 10° years. Suppose nuclear chemical analysis shows that there is 0.380 mmol of argon-40 for every 1.000 mmol of potassium-40 in a certain sample of rock. Calculate the age of the rock. Round your answer to 2 significant digits. |years x10 ?arrow_forwardIn a study of the gas phase decomposition of phosphine at 120 °C PH3(g)1/4 P(g) + 3/2 H2(g) the concentration of PH3 was followed as a function of time. It was found that a graph of In[PH3] versus time in seconds gave a straight line with a slope of -2.38×102s and a y-intercept of -2,47. Based on this plot, the reaction is order in PH3 and the rate constant for the reaction isarrow_forwardGive practical applications of chemical kinetics-related concepts in real life.arrow_forward
- Calculate the rate constant K round your answer to two significant digits.arrow_forwardScientists can determine the age of ancient objects by a method called radiocarbondating. The bombardment of the upper atmosphere by cosmic rays converts bitrogen toa radioactive isotope of carbon, C-14, with a half-life of about 5730 years. Vegetationabsorbs carbon dioxide through the atmosphere and animal life assimilates C-14 throughfood chains. When a plant or animal dies it stops replacing its carbon and the amount ofC-14 begins to decrease through radioactive decay. Therefore, the level of radioactivitymust also exponentially decay. A parchment fragment was discovered that had about74% as much C-14 radioactivity as does plant material on the earth today. Estimate theage of the parchment.arrow_forwardIn a study of the gas phase decomposition of dimethyl ether at 500 °C CH3OCH3(gCH,(g) + H2(g) + CO(g) the concentration of CH3OCH3 was followed as a function of time. It was found that a graph of In[CH3OCH3] versus time in seconds gave a straight line with a slope of -6.08×104 s and a y-intercept of -2.39 . Based on this plot, the reaction is | order in CH3OCH3 and the rate constant for the reaction isarrow_forward
arrow_back_ios
SEE MORE QUESTIONS
arrow_forward_ios
Recommended textbooks for you
- Physical ChemistryChemistryISBN:9781133958437Author:Ball, David W. (david Warren), BAER, TomasPublisher:Wadsworth Cengage Learning,Chemistry for Engineering StudentsChemistryISBN:9781337398909Author:Lawrence S. Brown, Tom HolmePublisher:Cengage Learning
- Chemistry: The Molecular ScienceChemistryISBN:9781285199047Author:John W. Moore, Conrad L. StanitskiPublisher:Cengage LearningChemistry: An Atoms First ApproachChemistryISBN:9781305079243Author:Steven S. Zumdahl, Susan A. ZumdahlPublisher:Cengage Learning
Physical Chemistry
Chemistry
ISBN:9781133958437
Author:Ball, David W. (david Warren), BAER, Tomas
Publisher:Wadsworth Cengage Learning,
Chemistry for Engineering Students
Chemistry
ISBN:9781337398909
Author:Lawrence S. Brown, Tom Holme
Publisher:Cengage Learning
Chemistry: The Molecular Science
Chemistry
ISBN:9781285199047
Author:John W. Moore, Conrad L. Stanitski
Publisher:Cengage Learning
Chemistry: An Atoms First Approach
Chemistry
ISBN:9781305079243
Author:Steven S. Zumdahl, Susan A. Zumdahl
Publisher:Cengage Learning
DISTINCTION BETWEEN ADSORPTION AND ABSORPTION; Author: 7activestudio;https://www.youtube.com/watch?v=vbWRuSk-BhE;License: Standard YouTube License, CC-BY
Difference Between Absorption and Adsorption - Surface Chemistry - Chemistry Class 11; Author: Ekeeda;https://www.youtube.com/watch?v=e7Ql2ZElgc0;License: Standard Youtube License