Chapter 11.2C, Problem 11.2P

(a)

Interpretation Introduction

To determine: The products of the reactions with the given compound.

Interpretation: The products of the reactions with the given compounds are to be stated.

Concept introduction: The combination of chromic acid or excess sodium hypochlorite with acetic acid is used for the conversion of secondary alcohols into ketone and primary alcohols into carboxylic acid through oxidation reaction.

The combination of $\text{PCC}\text{or}\text{NaOCl}\left(1\text{equivalent}\right)$ with $\text{TEMPO}$ is used for the conversion of primary alcohols into aldehyde and secondary alcohol into ketone through selective oxidation reaction.

(b)

Interpretation Introduction

To determine: The products of the reactions with the given compound.

Interpretation: The products of the reactions with the given compounds are to be stated.

Concept introduction: The combination of chromic acid or excess sodium hypochlorite with acetic acid is used for the conversion of secondary alcohols into ketone and primary alcohols into carboxylic acid through oxidation reaction.

The combination of $\text{PCC}\text{or}\text{NaOCl}\left(1\text{equivalent}\right)$ with $\text{TEMPO}$ is used for the conversion of primary alcohols into aldehyde and secondary alcohol into ketone through selective oxidation reaction.

(c)

Interpretation Introduction

To determine: The products of the reactions with the given compound.

Interpretation: The products of the reactions with the given compounds are to be stated.

Concept introduction: The combination of chromic acid or excess sodium hypochlorite with acetic acid is used for the conversion of secondary alcohols into ketone and primary alcohols into carboxylic acid through oxidation reaction.

The combination of $\text{PCC}\text{or}\text{NaOCl}\left(1\text{equivalent}\right)$ with $\text{TEMPO}$ is used for the conversion of primary alcohols into aldehyde and secondary alcohol into ketone through selective oxidation reaction.

(d)

Interpretation Introduction

To determine: The products of the reactions with the given compound.

Interpretation: The products of the reactions with the given compounds are to be stated.

Concept introduction: The combination of chromic acid or excess sodium hypochlorite with acetic acid is used for the conversion of secondary alcohols into ketone and primary alcohols into carboxylic acid through oxidation reaction.

The combination of $\text{PCC}\text{or}\text{NaOCl}\left(1\text{equivalent}\right)$ with $\text{TEMPO}$ is used for the conversion of primary alcohols into aldehyde and secondary alcohol into ketone through selective oxidation reaction.

(e)

Interpretation Introduction

To determine: The products of the reactions with the given compound.

Interpretation: The products of the reactions with the given compounds are to be stated.

Concept introduction: The combination of chromic acid or excess sodium hypochlorite with acetic acid is used for the conversion of secondary alcohols into ketone and primary alcohols into carboxylic acid through oxidation reaction.

The combination of $\text{PCC}\text{or}\text{NaOCl}\left(1\text{equivalent}\right)$ with $\text{TEMPO}$ is used for the conversion of primary alcohols into aldehyde and secondary alcohol into ketone through selective oxidation reaction.

(f)

Interpretation Introduction

To determine: The products of the reactions with the given compound.

Interpretation: The products of the reactions with the given compounds are to be stated.

Concept introduction: The combination of chromic acid or excess sodium hypochlorite with acetic acid is used for the conversion of secondary alcohols into ketone and primary alcohols into carboxylic acid through oxidation reaction.

The combination of $\text{PCC}\text{or}\text{NaOCl}\left(1\text{equivalent}\right)$ with $\text{TEMPO}$ is used for the conversion of primary alcohols into aldehyde and secondary alcohol into ketone through selective oxidation reaction.

(g)

Interpretation Introduction

To determine: The products of the reactions with the given compound.

Interpretation: The products of the reactions with the given compounds are to be stated.

Concept introduction: The combination of chromic acid or excess sodium hypochlorite with acetic acid is used for the conversion of secondary alcohols into ketone and primary alcohols into carboxylic acid through oxidation reaction.

The combination of $\text{PCC}\text{or}\text{NaOCl}\left(1\text{equivalent}\right)$ with $\text{TEMPO}$ is used for the conversion of primary alcohols into aldehyde and secondary alcohol into ketone through selective oxidation reaction.

(h)

Interpretation Introduction

To determine: The products of the reactions with the given compound.

Interpretation: The products of the reactions with the given compounds are to be stated.

Concept introduction: The combination of chromic acid or excess sodium hypochlorite with acetic acid is used for the conversion of secondary alcohols into ketone and primary alcohols or aldehyde into carboxylic acid through oxidation reaction.

The combination of $\text{PCC}\text{or}\text{NaOCl}\left(1\text{equivalent}\right)$ with $\text{TEMPO}$ is used for the conversion of primary alcohols into aldehyde and secondary alcohol into ketone through selective oxidation reaction.