Organic Chemistry (9th Edition)
9th Edition
ISBN: 9780321971371
Author: Leroy G. Wade, Jan W. Simek
Publisher: PEARSON
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Question
Chapter 11.12, Problem 11.31P
(a)
Interpretation Introduction
Interpretation:
The alcohol and the acid chloride that combines to make the given ester are to be stated.
Concept introduction:
An alcohol and an acid chloride mix together and form an ester with removal of hydrogen chloride. To neutralize the hydrogen chloride (side product), pyridine is used as a catalyst.
(b)
Interpretation Introduction
Interpretation:
The alcohol and the acid chloride that combines to make the given ester are to be stated.
Concept introduction:
An alcohol and an acid chloride mix together and form an ester with removal of hydrogen chloride. To neutralize the hydrogen chloride (side product), pyridine is used as a catalyst.
(c)
Interpretation Introduction
Interpretation:
The alcohol and the acid chloride that combines to make the given ester are to be stated.
Concept introduction:
An alcohol and an acid chloride mix together and form an ester with removal of hydrogen chloride. To neutralize the hydrogen chloride (side product), pyridine is used as a catalyst.
(d)
Interpretation Introduction
Interpretation:
The alcohol and the acid chloride that combines to make the given ester are to be stated.
Concept introduction:
An alcohol and an acid chloride mix together and form an ester with removal of hydrogen chloride. To neutralize the hydrogen chloride (side product), pyridine is used as a catalyst.
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Ester compounds often have a sweet, pleasant odor. Many
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Alcohols for Air Freshener Project
Molar mass Density Cost, per
(g/mL)
Reagent
(g/mol)
1.00 L
methanol
32.04
0.79
$46.20
ethanol
46.07
0.79
$112.00
1-propanol
60.10
0.80
$72.70
1-butanol
74.12
0.81
$72.60
Use the structural formulas of the alcohols and…
Test tube one has Acetic Acid and Benzyl Alcohol. Test tube two has Salicyclic Acid and methanol. Then in test tube three has Cinnamic Acid and Ethanol.
Which of the esters' molecular structures contain an aromatic ring?
Draw a compound with the molecular formula C7H12O2 that contains an ester
Chapter 11 Solutions
Organic Chemistry (9th Edition)
Ch. 11.1 - Prob. 11.1PCh. 11.2C - Prob. 11.2PCh. 11.3 - Prob. 11.3PCh. 11.3 - Prob. 11.4PCh. 11.3 - Prob. 11.5PCh. 11.3 - Suggest the most appropriate method for each of...Ch. 11.4 - A chronic alcoholic requires a much larger dose of...Ch. 11.4 - Unlike ethylene glycol, propylene glycol...Ch. 11.5 - Predict the major products of the following...Ch. 11.5 - Show how you would convert propan-1-ol to the...
Ch. 11.6 - Predict the products of the following reactions....Ch. 11.7A - Propose a mechanism for the reaction of a....Ch. 11.7B - Prob. 11.13PCh. 11.7B - Show how you would use a simple chemical test to...Ch. 11.7C - Neopentyl alcohol, (CH3)3CCH2OH, reacts with...Ch. 11.7C - Prob. 11.16PCh. 11.7C - When cis-2-methylcyclohexanol reacts with the...Ch. 11.8 - Prob. 11.18PCh. 11.9 - Prob. 11.19PCh. 11.9 - Prob. 11.20PCh. 11.9 - Prob. 11.21PCh. 11.10A - Prob. 11.22PCh. 11.10A - Some alcohols undergo rearrangement or other...Ch. 11.10B - Prob. 11.24PCh. 11.10B - Explain why the acid-catalyzed condensation is a...Ch. 11.10B - Prob. 11.26PCh. 11.10B - When the following substituted cycloheptanol...Ch. 11.11A - Prob. 11.28PCh. 11.11A - Prob. 11.29PCh. 11.11B - Predict the products formed by periodic acid...Ch. 11.12 - Prob. 11.31PCh. 11.13A - Prob. 11.32PCh. 11.14 - Prob. 11.33PCh. 11.14 - a. Show how ethanol and cyclohexanol may be used...Ch. 11.14 - Prob. 11.35PCh. 11.14 - Phenols (pKa 10) are more acidic than other...Ch. 11.14 - To practice working through the early parts of a...Ch. 11.14 - Prob. 11.38PCh. 11 - Predict the major products of the following...Ch. 11 - Show how you would convert 2-methylcyclopentanol...Ch. 11 - In each case, show how you would synthesize the...Ch. 11 - Prob. 11.42SPCh. 11 - Prob. 11.43SPCh. 11 - Prob. 11.44SPCh. 11 - Both cis- and trans-2-methylcyclohexanol undergo...Ch. 11 - Prob. 11.46SPCh. 11 - Prob. 11.47SPCh. 11 - Show how you would make each compound, beginning...Ch. 11 - Predict the major products (including...Ch. 11 - Show how you would use simple chemical tests to...Ch. 11 - The compound shown below has three different types...Ch. 11 - Prob. 11.52SPCh. 11 - Prob. 11.53SPCh. 11 - Prob. 11.54SPCh. 11 - Prob. 11.55SPCh. 11 - Show how you would synthesize the following...Ch. 11 - Show how you would synthesize the following...Ch. 11 - The following pseudo-syntheses (guaranteed not to...Ch. 11 - Two unknowns, X and Y, both having the molecular...Ch. 11 - The Williamson ether synthesis involves the...Ch. 11 - Prob. 11.61SPCh. 11 - Prob. 11.62SPCh. 11 - Alcohols combine with ketones and aldehydes to...Ch. 11 - Prob. 11.64SPCh. 11 - Prob. 11.65SPCh. 11 - Prob. 11.66SP
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- does acetaminophen (tylenol) contain an ester functional group? explainarrow_forward1. Draw the Full Lewis chemical structure of a simple ester of your choice containing exactly five carbon atoms.arrow_forwardFollowing is an ---- and called ---, respectively. ester, methyl hexanoate ester, methyl butanoate ester, ethyl pentanoate ether, methyl butanoatearrow_forward
- What is the functional group of propanoic acid? How do we know if it's soluble in water or insluble in water using the flowchart that is attached. which test should be performed using the flowchart. Is propanoic acid a ketone, aldehyde, ester or alcohol and how did you know?what would be the most efficient series of solubility and functional group tests that would identify the functional group? Also what could be the sources of error in this experiment? What could occur that would give false positives, false negatives, or incorrect interpretations?arrow_forwardWhy is aqueous ammonia used in a reaction with an ester to produce an amide and alcohol? Why not use alcoholic ammonia?arrow_forwardDraw an ester with the formula C3H6O2 AND Draw the structures for a specific aldehyde and a specific ketone that have the formula C3H6Oarrow_forward
- 3) Which one(s) of the following is/are an acetal ?arrow_forwardIdentify the functional groups in the two molecules shown below. Then, for each ester or amide functional group, write a reaction showing how the molecule could be made. H. H.arrow_forwardPhenols are aromatic rings with an alcohol functional group attached directly to the ring. These compounds have unique acidity and solubility for alcohol groups. Predict the solubility of this phenol in water.arrow_forward
- Explain why methanol and water are completely miscible, while pentanol is only slightly soluble in water?arrow_forwardBriefly explain the following. Why hydrolysis of esters produce a sour smell in some reactions? Why are alcohol solutions used in hydroxamic test for esters?arrow_forwardIs this an alcohol, carboxylic acid, or phenol? Why?arrow_forward
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