EBK ORGANIC CHEMISTRY-PRINT COMPANION (
4th Edition
ISBN: 9781119776741
Author: Klein
Publisher: WILEY CONS
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Chapter 9.5, Problem 12CC
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Interpretation: To determine the structure of
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- When the conjugate acid of aniline, C6H5NH3+, reacts with the acetate ion, the following reaction takes place: C6H5NH3+(aq)+CH3COO(aq)C6H5NH2(aq)+CH3COOH(aq) If Kafor C6H5NH3+ is 1.35105 and Kafor CH3COOH is 1.86105 , what is K for the reaction?arrow_forwardWhich alcohols can be prepared as a single product by hydroboration– oxidation of an alkene? Which alcohols can be prepared as a single product by the acid-catalyzed addition of H2O to an alkene?arrow_forwardWhich alcohols can be prepared as a single product by hydroboration–oxidation of an alkene? Which alcohols can be prepared as a singleproduct by the acid-catalyzed addition of H2O to an alkene?arrow_forward
- a) What products would you expect from the elimination reaction of 3-Bromo-2- methylpentane? Show the reaction by writing the condensed structural formula of the reactants and products. Identify the major and minor products. b) What alkyl halide might the 3,6-Dimethyl-1- heptene have been made from?arrow_forwardCompound A is unsaturated hydrocarbon with molecular formula (C6H12) reacted with Br2 in water to form compound B. compound C was produced from the reaction between compound A, sulphuric acid and H2O (g). Compound A undergo hydrogenation to form compound D. Compound E was produced from the reaction of compound A with Br2 in room temperature. Compound A undergo hydrohalogenation in the presences of hydrogen peroxide to form compound F. The reaction between compound F with aqueous sodium hydroxide will form compound G. Compound H was produced when compound F reacts with the aqueous ammonia in ethanol. Compound F also reacts with aqueous sodium cyanide to produce compound I. Draw the possible structural formulae of compounds A, B, C, D, E, F, G, H and I. Give the IUPAC nomenclature of compounds H and I. Distinguish between compound A and D.arrow_forwardDraw the products formed when alkene reacts with these reagents: (i) H2 in the presence of Pd catalyst, (ii) HCl.arrow_forward
- Compound A is an alkyne that reacts with two equivalents of H2 in the presence of Pd to give 2,4,6-trimethyloctane. Draw the structure of compound A.arrow_forward5B In the following reactions, mixtures of alkenes and ethyl ethers are formed. Draw their structures. Explain which is or are likely to be the main product(s) in each reaction. In case of formation of two isomers of alkenes, explain which is formed in greater proportion CH3 CH3 H3C-C H -Br CH3 EtOHarrow_forwardAlkenes can be converted to alcohols by reaction with mercuric acetate to form a β-hydroxyalkylmercury(II) acetate compound, a reaction called oxymercuration. Subsequent reduction with NaBH4 reduces the C–Hg bond to a C–H bond, forming the alkyl alcohol, a reaction called demercuration. Draw the structures of the Hg-containing compound(s) and the final alcohol product(s) formed in the following reaction sequence, omitting byproducts. If applicable, draw hydrogen at a chirality center and indicate stereochemistry via wedge-and-dash bonds.arrow_forward
- 2-chloropropane is a major product of the reaction of chlorine with propane under ultraviolet light. Write the mechanism for this reaction including the initiation step and the two propagation steps.arrow_forwardExplain addition of H2O to an alkyne ?arrow_forwardLactones, cyclic esters such as compound A, are prepared by halolactonization, an addition reaction to an alkene. For example, iodolactonization of B forms lactone C, a key intermediate in the synthesis of prostaglandin PGF2α (Section 4.15). Draw a stepwise mechanism for this addition reaction.arrow_forward
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