Concept explainers
(a)
Interpretation: The structure corresponding to the given name is to be drawn.
Concept introduction: To derive the structure of the compound from its IUPAC name, one should follow the given three steps. The first step involves the identification of parent name and
Answer to Problem 9.42P
The structure corresponding to the given name is,
Explanation of Solution
The name of the given compound is
Figure 1
The structure corresponding to the given name is shown in Figure 1.
(b)
Interpretation: The structure corresponding to the given name is to be drawn.
Concept introduction: To derive the structure of the compound from its IUPAC name, one should follow the given three steps. The first step involves the identification of parent name and functional group found at the end of the name. The second step is numbering of carbon skeleton in either direction. The third step is addition of substituents at appropriate carbon atoms.
Answer to Problem 9.42P
The structure corresponding to the given name is,
Explanation of Solution
The name of the given compound is
Figure 2
The structure corresponding to the given name is shown in Figure 2.
(c)
Interpretation: The structure corresponding to the given name is to be drawn.
Concept introduction: To derive the structure of the compound from its IUPAC name, one should follow the given three steps. The first step involves the identification of parent name and functional group found at the end of the name. The second step is numbering of carbon skeleton in either direction. The third step is addition of substituents at appropriate carbon atoms.
Answer to Problem 9.42P
The structure corresponding to the given name is,
Explanation of Solution
The name of the given compound is
Figure 3
The structure corresponding to the given name is shown in Figure 3.
(d)
Interpretation: The structure corresponding to the given name is to be drawn.
Concept introduction: To derive the structure of the compound from its IUPAC name, one should follow the given three steps. The first step involves the identification of parent name and functional group found at the end of the name. The second step is numbering of carbon skeleton in either direction. The third step is addition of substituents at appropriate carbon atoms.
Answer to Problem 9.42P
The structure corresponding to the given name is,
Explanation of Solution
The name of the given compound is
Figure 4
The structure corresponding to the given name is shown in Figure 4.
(e)
Interpretation: The structure corresponding to the given name is to be drawn.
Concept introduction: To derive the structure of the compound from its IUPAC name, one should follow the given three steps. The first step involves the identification of parent name and functional group found at the end of the name. The second step is numbering of carbon skeleton in either direction. The third step is addition of substituents at appropriate carbon atoms.
Answer to Problem 9.42P
The structure corresponding to the given name is,
Explanation of Solution
The name of the given compound is
Figure 5
The structure corresponding to the given name is shown in Figure 5.
(f)
Interpretation: The structure corresponding to the given name is to be drawn.
Concept introduction: To derive the structure of the compound from its IUPAC name, one should follow the given three steps. The first step involves the identification of parent name and functional group found at the end of the name. The second step is numbering of carbon skeleton in either direction. The third step is addition of substituents at appropriate carbon atoms.
Answer to Problem 9.42P
The structure corresponding to the given name is,
Explanation of Solution
The name of the given compound is
Figure 6
The structure corresponding to the given name is shown in Figure 6.
(g)
Interpretation: The structure corresponding to the given name is to be drawn.
Concept introduction: To derive the structure of the compound from its IUPAC name, one should follow the given three steps. The first step involves the identification of parent name and functional group found at the end of the name. The second step is numbering of carbon skeleton in either direction. The third step is addition of substituents at appropriate carbon atoms.
The naming of chiral center and geometric isomers are based on Cahn-Ingold-Prelog priority rules. If the priority assigned to each group attached to the chirality center in a molecule is in a clockwise direction, then it is the R-stereoisomer, and if this is counter-clockwise, then it is the S-stereoisomer. R and S-stereoisomer are mirror images of each other.
Answer to Problem 9.42P
The structure corresponding to the given name is,
Explanation of Solution
The name of the given compound is
Figure 7
The structure corresponding to the given name is shown in Figure 7.
(h)
Interpretation: The structure corresponding to the given name is to be drawn.
Concept introduction: To derive the structure of the compound from its IUPAC name, one should follow the given three steps. The first step involves the identification of parent name and functional group found at the end of the name. The second step is numbering of carbon skeleton in either direction. The third step is addition of substituents at appropriate carbon atoms.
The naming of chiral center and geometric isomers are based on Cahn-Ingold-Prelog priority rules. If the priority assigned to each group attached to the chirality center in a molecule is in a clockwise direction, then it is the R-stereoisomer, and if this is counter-clockwise, then it is the S-stereoisomer. R and S-stereoisomer are mirror images of each other.
Answer to Problem 9.42P
The structure corresponding to the given name is,
Explanation of Solution
The name of the given compound is
Figure 8
The structure corresponding to the given name is shown in Figure 8.
(i)
Interpretation: The structure corresponding to the given name is to be drawn.
Concept introduction: To derive the structure of the compound from its IUPAC name, one should follow the given three steps. The first step involves the identification of parent name and functional group found at the end of the name. The second step is numbering of carbon skeleton in either direction. The third step is addition of substituents at appropriate carbon atoms.
Answer to Problem 9.42P
The structure corresponding to the given name is,
Explanation of Solution
The name of the given compound is
Figure 9
The structure corresponding to the given name is shown in Figure 9.
(j)
Interpretation: The structure corresponding to the given name is to be drawn.
Concept introduction: To derive the structure of the compound from its IUPAC name, one should follow the given three steps. The first step involves the identification of parent name and functional group found at the end of the name. The second step is numbering of carbon skeleton in either direction. The third step is addition of substituents at appropriate carbon atoms.
Answer to Problem 9.42P
The structure corresponding to the given name is,
Explanation of Solution
The name of the given compound is
Figure 10
The structure corresponding to the given name is shown in Figure 10.
Want to see more full solutions like this?
Chapter 9 Solutions
Organic Chemistry
- 1. Give the IUPAC name for the following structures. 6-methylhept-4-en-2-one hig a. C. 5-isopropyl-2-heptanone HO pentan-2-yl-5-bromoheptanoate m la Ďarrow_forwardWhich is the major organic product of this reaction? A. B. 4 ОА O OB O C COD AICI3 benzene C. D.arrow_forwardDraw the structure corresponding to each name.a. 3,3-dimethylpentanoic acidb. 4-chloro-3-phenylheptanoic acidc. (R)-2-chloropropanoic acidd. m-hydroxybenzoic acide. potassium acetatef. sodium α-bromobutyrateg. 2,2-dichloropentanedioic acidh. 4-isopropyl-2-methyloctanedioic acidi. 3,3-dimethylpentanenitrile j. 4,5-diethyl-2-isopropylnonanenitrilearrow_forward
- Draw the products formed when p-methylaniline (p-CH3C6H4NH2) is treated with each reagent. a. HCl b. CH3COCl c. (CH3CO)2O d. excess CH3I e. (CH3)2C = O f. CH3COCl, AlCl3 g. CH3CO2H h. NaNO2, HCl i. Part (b), then CH3COCl, AlCl j. CH3CHO, NaBH3CNarrow_forwardGive the structure corresponding to each name. a. 5,6-dimethylhept-2-yne b. 5-tert-butyl-6,6-dimethylnon-3-yne c. (S)-4-chloropent-2-yne d. cis-1-ethynyl-2-methylcyclopentane e. 3,4-dimethylocta-1,5-diyne f. (Z)-6-methyloct-6-en-1-ynearrow_forwardDraw the products formed when ethylene oxide is treated with each reagent. a. HBr b. H2O(H2SO4) c. [1] CH3CH2O; [2] H2O d. [1] HC ≡ C−; [2] H2O e. [1] −OH; [2] H2O f. [1] CH3S−; [2] H2Oarrow_forward
- What is the correct name of this compound ? H3C-C CH-CH-CH2-CH3 OH O a. 5-phenoxy-4-hexen-3-ol O b. 2-phenoxy-2-hexen-4-ol O c. 4-hexen-3-ol phenyl ether O d. 4-hydroxy-2-phenoxy-2-hexenearrow_forwardDoes the equilibrium favor the reactants or products in each substitution reaction? a. CH;CH2-NH2 Br CH;CH2-Br + "NH2 b. "CN CN + I-arrow_forwardcis-Cyclohexane-1,2-diol can be synthesized from cyclohexene by using which reagent? a.O3 b.OsO4 c.H2SO4 d.mCPBAarrow_forward
- Draw the organic product(s) formed when CH3CH2CH2OH is treated with each reagent. a.H2SO4 b.NaH c.HCl + ZnCl2 d.HBr e.SOCl2, pyridine f.PBr3 g.TsCl, pyridine h. [1] NaH; [2] CH3CH2Br [1] i.TsCl, pyridine; [2] NaSH j.POCl3, pyridinearrow_forwardWhat is the organic product of the following reaction? ? + 2CH3OH A. C. OH H* E. None of the Above CH3O OCH3 B. D. 10arrow_forward22. How many of these reactions produce a product named 2-butanol? H₂SO4 H₂O A Br₂ CH₂Cl₂ A. 1 B. 2 C. 3 D. 4 E. 5 1.03 2. Zn/H₂O 1. BH 2. HyOz, NaOH 1. Hg(OAc)2, H₂O 2. NaBH4arrow_forward
- ChemistryChemistryISBN:9781305957404Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCostePublisher:Cengage LearningChemistryChemistryISBN:9781259911156Author:Raymond Chang Dr., Jason Overby ProfessorPublisher:McGraw-Hill EducationPrinciples of Instrumental AnalysisChemistryISBN:9781305577213Author:Douglas A. Skoog, F. James Holler, Stanley R. CrouchPublisher:Cengage Learning
- Organic ChemistryChemistryISBN:9780078021558Author:Janice Gorzynski Smith Dr.Publisher:McGraw-Hill EducationChemistry: Principles and ReactionsChemistryISBN:9781305079373Author:William L. Masterton, Cecile N. HurleyPublisher:Cengage LearningElementary Principles of Chemical Processes, Bind...ChemistryISBN:9781118431221Author:Richard M. Felder, Ronald W. Rousseau, Lisa G. BullardPublisher:WILEY