a) Aqueous acidic KMnO 4 Interpretation: The product expected when 1-methylcyclohexene reacts with aqueous acidic KMnO 4 is to be stated. Concept introduction: Potassium permanganate in neutral or aqueous acidic solutions cleaves the double bonds in alkenes to give carbonyl containing products. If the carbons in double bond are mono-substituted, carboxylic acids are produced, if they are di-substituted, ketones are produced. To state: The product expected when 1-methylcyclohexene reacts with aqueous acidic KMnO 4 .

Question

Propose products (if any) reactions:(a) chlorocyclohexane with benzene

Answer 1

Question

Definition Definition Class of organic compounds that contain a carboxyl group ( - COOH ) and has a general formula R - COOH or R - CO 2 H , where R refers to the alkyl, alkenyl, aryl, or other groups. They can undergo different chemical reactions, such as acid-base reactions, esterification, and oxidation. These are essential components of living organisms, playing important roles in metabolic processes, signaling, and as pharmaceuticals.

Chapter 8.8, Problem 15P

Interpretation Introduction

a) Aqueous acidic KMnO₄

Interpretation:

The product expected when 1-methylcyclohexene reacts with aqueous acidic KMnO₄ is to be stated.

Concept introduction:

Potassium permanganate in neutral or aqueous acidic solutions cleaves the double bonds in alkenes to give carbonyl containing products. If the carbons in double bond are mono-substituted, carboxylic acids are produced, if they are di-substituted, ketones are produced.

To state:

The product expected when 1-methylcyclohexene reacts with aqueous acidic KMnO₄.

Interpretation Introduction

b)

Interpretation:

The product expected when 1-methylcyclohexene reacts with O₃, followed by Zn, CH₃COOH is to be stated.

Concept introduction:

Ozone adds to the double bond in alkenes to produce compounds called ozonides. The ozonides upon immediate treatment with Zn and acetic acid yield carbonyl compounds. Each carbon in the double bond cleaved gets attached to an oxygen atom. A di-substituted carbon in double bond gives a ketone while a mono-substituted carbon in double bond gives a ketone and an aldehyde as products.

To state:

The product expected when 1-methylcyclohexene reacts with O₃, followed by Zn, CH₃COOH.

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Propose products (if any) reactions:(a) chlorocyclohexane with benzene

Please give the main substitution product for each of the following reactions, and indicate the dominant mechanism: (a) 1-bromopropane + NaOCH3 → (b) 3-bromo-3-methylpentane + NaOC2H5 →

What alkene is needed to synthesize each 1,2-diol using [1] OsO4 followed by NaHSO3 in H2O; or [2] CH3CO3H followed by −OH in H2O?

Answer 2

Question

Definition Definition Class of organic compounds that contain a carboxyl group ( - COOH ) and has a general formula R - COOH or R - CO 2 H , where R refers to the alkyl, alkenyl, aryl, or other groups. They can undergo different chemical reactions, such as acid-base reactions, esterification, and oxidation. These are essential components of living organisms, playing important roles in metabolic processes, signaling, and as pharmaceuticals.

Chapter 8.8, Problem 15P

Interpretation Introduction

a) Aqueous acidic KMnO₄

Interpretation:

The product expected when 1-methylcyclohexene reacts with aqueous acidic KMnO₄ is to be stated.

Concept introduction:

Potassium permanganate in neutral or aqueous acidic solutions cleaves the double bonds in alkenes to give carbonyl containing products. If the carbons in double bond are mono-substituted, carboxylic acids are produced, if they are di-substituted, ketones are produced.

To state:

The product expected when 1-methylcyclohexene reacts with aqueous acidic KMnO₄.

Interpretation Introduction

b)

Interpretation:

The product expected when 1-methylcyclohexene reacts with O₃, followed by Zn, CH₃COOH is to be stated.

Concept introduction:

Ozone adds to the double bond in alkenes to produce compounds called ozonides. The ozonides upon immediate treatment with Zn and acetic acid yield carbonyl compounds. Each carbon in the double bond cleaved gets attached to an oxygen atom. A di-substituted carbon in double bond gives a ketone while a mono-substituted carbon in double bond gives a ketone and an aldehyde as products.

To state:

The product expected when 1-methylcyclohexene reacts with O₃, followed by Zn, CH₃COOH.

Expert Solution & Answer

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See solution

Check out sample textbook solution

Answer 3

Question

Definition Definition Class of organic compounds that contain a carboxyl group ( - COOH ) and has a general formula R - COOH or R - CO 2 H , where R refers to the alkyl, alkenyl, aryl, or other groups. They can undergo different chemical reactions, such as acid-base reactions, esterification, and oxidation. These are essential components of living organisms, playing important roles in metabolic processes, signaling, and as pharmaceuticals.

Chapter 8.8, Problem 15P

Interpretation Introduction

a) Aqueous acidic KMnO₄

Interpretation:

The product expected when 1-methylcyclohexene reacts with aqueous acidic KMnO₄ is to be stated.

Concept introduction:

Potassium permanganate in neutral or aqueous acidic solutions cleaves the double bonds in alkenes to give carbonyl containing products. If the carbons in double bond are mono-substituted, carboxylic acids are produced, if they are di-substituted, ketones are produced.

To state:

The product expected when 1-methylcyclohexene reacts with aqueous acidic KMnO₄.

Interpretation Introduction

b)

Interpretation:

The product expected when 1-methylcyclohexene reacts with O₃, followed by Zn, CH₃COOH is to be stated.

Concept introduction:

Ozone adds to the double bond in alkenes to produce compounds called ozonides. The ozonides upon immediate treatment with Zn and acetic acid yield carbonyl compounds. Each carbon in the double bond cleaved gets attached to an oxygen atom. A di-substituted carbon in double bond gives a ketone while a mono-substituted carbon in double bond gives a ketone and an aldehyde as products.

To state:

The product expected when 1-methylcyclohexene reacts with O₃, followed by Zn, CH₃COOH.

Expert Solution & Answer

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See solution

Check out sample textbook solution

Answer 4

Question

Definition Definition Class of organic compounds that contain a carboxyl group ( - COOH ) and has a general formula R - COOH or R - CO 2 H , where R refers to the alkyl, alkenyl, aryl, or other groups. They can undergo different chemical reactions, such as acid-base reactions, esterification, and oxidation. These are essential components of living organisms, playing important roles in metabolic processes, signaling, and as pharmaceuticals.

Chapter 8.8, Problem 15P

Interpretation Introduction