(a)
To determine: The product for the m-chloroperoxybenzoic acid epoxidation of
Interpretation: The product for the m-chloroperoxybenzoic acid epoxidation of
Concept introduction: Epoxidation of alkene is an oxidation process.
(b)
To determine: The product for the m-chloroperoxybenzoic acid epoxidation of
Interpretation: The product for the m-chloroperoxybenzoic acid epoxidation of
Concept introduction: Epoxidation of alkene is an oxidation process. Epoxides are also called an oxirane and they are intermediates that are used to convert alkenes into other functional group. Peroxyacid is used to convert alkene into an epoxide.
(c)
To determine: The product for the m-chloroperoxybenzoic acid epoxidation of
Interpretation: The product for the m-chloroperoxybenzoic acid epoxidation of
Concept introduction: Epoxidation of alkene is an oxidation process. Epoxides are also called an oxirane and they are intermediates that are used to convert alkenes into other functional group. Peroxyacid is used to convert alkene into an epoxide.
(d)
To determine: The product for the m-chloroperoxybenzoic acid epoxidation of
Interpretation: The product for the m-chloroperoxybenzoic acid epoxidation of
Concept introduction: Epoxidation of alkene is an oxidation process. Epoxides are also called an oxirane and they are intermediates that are used to convert alkenes into other functional group. Peroxyacid is used to convert alkene into an epoxide.
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Chapter 8 Solutions
Organic Chemistry (9th Edition)
- What is the best set of reagents to achieve deoxygenation of 2-pentanone to pentane? A. NaClO2/NaH2PO4 B. LiAlH4, Et2O C. DIBAL-H, THF D. NH2NH2/t-BuOK, DMSOarrow_forward43. Identify the reagent that will produce the following brominated product in greatest amount. Br A. Br₂/uv ? B. Br2/FeBr3 C. NBS D. Br2/CC14 44. Under acidic condition, which of the following compounds can not be oxidized by KMnO4. A. toluene B. 2-butene C. methylcyclohexane D. 2-butynearrow_forwardThe preperaation of 3-bromo-5-nitrobenzoic acid follows which reaction steps a.oxidation, nitration, bromination b.nitration, bromination, alkylation, oxidation c.bromination, alkylation, oxidation, nitration d.alkylation, oxidation, nitration, brominationarrow_forward
- - How could the following changes in reaction conditions affect the rate of the reaction when isopropanol (IPA) reacts with 2-bromo-2-methylpentane? The concentration of the IPA is halved by adding petroleum ether as the solvent. b. The concentration of the bromoalkene is quadrupled. а.arrow_forwardselect reagents: cyclopentanone Reagents a. C6H5CHO b. NaOH, ethanol c. Pyrrolidine, cat. Hj. d. H₂C=CHCN e. H3O+ f. LDA g. A) bg EtOC(=O)CO₂Et h. i. B) ka k. I. m. O: BrCH₂CH=CH₂ NatOEt, ethanol Br₂, H+ K+ t-BUO™ CH2(CO2Et)z heat C) jh CO₂Et D) Imarrow_forwardConsider the reaction of chloro, bromo, and iodocyclohexane with KOH to give the elimination product cyclohexene. a. Assuming the mechanism is El, which should react faster and why? b. Write the El mechanism for the reaction of iodocyclohexane with KOH. c. Write the E2 mechanism for the reaction of chlorocyclohexane with KOH.arrow_forward
- 2. Name and Draw the structures p-chloroaniline of all possible chemical (Electrophilic aronmatic substitution) reactions of the compound namely a. Halogenation (Chlorination or Bromination) b. Nitration c. Sulphonation d. Friedal Craft Alkylation e. Eriedal Craft Acylationarrow_forward4. Write in the product, including stereochemistry where relevant, for these reactions. a) b) cyclohexene 1-pentene 1. Os04 2. NaHSO3 1. 03 2. Zn, H* →→arrow_forwardStarting Materials CH3B CH3CH2BR CH3CH2CH,Br C6H5Br Reagents Mg, ether 1. a. 2. 13CH2-13C-OH b. 13CO2 then H3O* 3. LIAIH4 then H3o* PBr3 CO2 then H30* C. 4. d. 5. C6HsCH2Br е. Select a starting material and a series of reagents necessary to synthesize this compound in as few steps as possible. Enter your selection as a number for the starting material, followed by the letters of the reagents, in the order that you wish to use them, i.e. 3abcf.arrow_forward
- Which of the provided schemes can be used to synthesize p-chlorophenol p-chlorophenol from benzen e? A. None of the below schemes are correct B. O C. D. SO3 H₂SO4 Cl₂ FeCl 903 H₂SO4 Product Product Product 1. NaOH 2. H₂O* SO 3 H₂SO4 Cl₂ FeCl Product Product Product Cl₂ FeCl H₂/Pd 1. NaOH 2. H₂O* p-Chlorophenol p-Chlorophenol p-Chlorophenolarrow_forwardWhich of the following alkylhalides is used in the synthesis of 2-hexanone? a. CH;CH2B., CH;COCH2COOET b. CH3CH2CH2Br, CH3COCH2COOEt c. BRCH2CH2CH;Br, E1OOCCH;COOEt d. CH;CH2CH,Br, E1OOCCH2COOE.arrow_forward1. Predict the products, if any, for the reaction of benzene with the following reagents: a. Br2/CCl4, room temperature b. C2H5Cl, AlCl3arrow_forward
Organic ChemistryChemistryISBN:9781305580350Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. FootePublisher:Cengage Learning