Chemistry: Principles and Reactions
8th Edition
ISBN: 9781305079373
Author: William L. Masterton, Cecile N. Hurley
Publisher: Cengage Learning
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Chapter 19, Problem 43QAP
Ti(NH3)63+ has a d-orbital electron transition at 399 nm. Find Δo at this wavelength.
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The octahedral complex [Ti(H2O)6]3+ has a single d electron. To excite this electron from the ground state t2g orbital to the eg orbital, this complex absorbs light from 450 to 600 nm. The maximum absorbance corresponds to Δoct and occurs at 499 nm. Calculate the value of Δoct in Joules and predict what color the solution will appear.
Chapter 19 Solutions
Chemistry: Principles and Reactions
Ch. 19 - Prob. 1QAPCh. 19 - Prob. 2QAPCh. 19 - Prob. 3QAPCh. 19 - Platinum(II) forms many complexes, among them...Ch. 19 - Prob. 5QAPCh. 19 - What is the coordination number of the central...Ch. 19 - Prob. 7QAPCh. 19 - Prob. 8QAPCh. 19 - Prob. 9QAPCh. 19 - Prob. 10QAP
Ch. 19 - Prob. 11QAPCh. 19 - Prob. 12QAPCh. 19 - What is the mass percent of sulfur in the...Ch. 19 - Prob. 14QAPCh. 19 - There are four iron atoms in each hemoglobin...Ch. 19 - Vitamin B12 is a coordination compound with cobalt...Ch. 19 - Prob. 17QAPCh. 19 - Prob. 18QAPCh. 19 - Name the following ions or compounds (a)...Ch. 19 - Name the following ions or compounds (a)...Ch. 19 - Prob. 21QAPCh. 19 - Prob. 22QAPCh. 19 - Sketch the geometry of (a)...Ch. 19 - Sketch the geometry of (a) tans-[Cu(Br)2(H2O)4]...Ch. 19 - Prob. 25QAPCh. 19 - Prob. 26QAPCh. 19 - Which of the following octahedral complexes show...Ch. 19 - Prob. 28QAPCh. 19 - Prob. 29QAPCh. 19 - Prob. 30QAPCh. 19 - Prob. 31QAPCh. 19 - Prob. 32QAPCh. 19 - Write an abbreviated orbital diagram and determine...Ch. 19 - Prob. 34QAPCh. 19 - Give the electron distribution in low-spin and/or...Ch. 19 - Prob. 36QAPCh. 19 - Prob. 37QAPCh. 19 - Prob. 38QAPCh. 19 - Prob. 39QAPCh. 19 - Prob. 40QAPCh. 19 - Give the number of unpaired electrons in...Ch. 19 - Prob. 42QAPCh. 19 - Ti(NH3)63+ has a d-orbital electron transition at...Ch. 19 - has a crystal field splitting energy, o, of...Ch. 19 - Prob. 45QAPCh. 19 - Prob. 46QAPCh. 19 - Prob. 47QAPCh. 19 - Prob. 48QAPCh. 19 - Prob. 49QAPCh. 19 - Indicate whether each of the following is true or...Ch. 19 - A child eats 10.0 g of paint containing 5.0% Pb....Ch. 19 - A certain coordination compound has the simplest...Ch. 19 - Prob. 53QAPCh. 19 - In the [Ti(H2O)63+] ion, the splitting between the...
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- Identify, based on the position in the periodic table, the actinide elements among those in the following list: Co, Cm, Cd, Ce, Cf.arrow_forwardPlatinum(II) forms many complexes, among them those with the following ligands. Give the formula and charge of each complex. (a) two ammonia molecules and one oxalate ion (C2O42-) (b) two ammonia molecules, one thiocyanate ion (SCN-), and one bromide ion (c) one ethylenediamine molecule and two nitrite ionsarrow_forwardAn aqueous solution of [Rh(C2O4)3]3− is yellow. Predict the approximate wavelength and predominant color of light absorbed by the complex.arrow_forward
- Identify a cation of a first series transition metal that is isoelectronic with each of the following. (a) Fe3+ (b) Zn2+ (c) Fe2+ (d) Cr3+arrow_forwardThe complexes [V(H2O)6]3+ and [VF6]3- are both known. Which of the two complexes would you expect to absorb light of higher energy?arrow_forwardAarange the following in increasing order of acidity and provide reason for same: [Fe(OH2)6]2+, [Al(OH2)6]3+,[Fe(OH2)6]3+.arrow_forward
- In which one of the following species does the transition metal ion have d electronic configuration? O (Co(OH2)62+ O (CoFa3- O (Ni(OH,)J2+arrow_forwardWhich of the following transition metal ions has a d⁵ electron configuration? A) Fe³⁺ B) Co³⁺ C) V⁴⁺ D) Ir⁺ E) Fe²⁺arrow_forwardthe d-d transition of [Ti(H2O)6]3+ produces an absorption maximum at a wavelength of about 500 nm. What is the magnitude of ∆ for [Ti(H2O)6]3+ in kJ/mol?arrow_forward
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