Chemistry: Principles and Reactions
8th Edition
ISBN: 9781305079373
Author: William L. Masterton, Cecile N. Hurley
Publisher: Cengage Learning
expand_more
expand_more
format_list_bulleted
Concept explainers
Textbook Question
Chapter 14, Problem 48QAP
A 0.2481 M solution of KOH is used to titrate 30.00 mL of 0.269 M hydrobromic acid. Assume that volumes are additive.
(a) Write a balanced net ionic equation for the reaction that takes place during the titration.
(b) What are the species present at the equivalence point?
(c) What volume of KOH is required to reach the equivalence point?
(d) What is the pH of the solution
1. before any KOH is added?
2. halfway to the equivalence point?
3. at the equivalence point?
Expert Solution & Answer
Trending nowThis is a popular solution!
Students have asked these similar questions
A solution NH3 that contains 72 mL of 0.043 M ammonia, NH3, is titrated with 0.083 M HCl. The Kb of ammonia is 1.8x10-5.
(a) What volume of 0.083 M HCI would be added to reach the equivalence point? Give the volume in mL.
49 37
mL
(b) At the equivalence point, what is the pH of the solution? (Assume that volumes are additive.)
40
8.98
X
whawhat "at onubralence point" implies about the quantities of the combined acids and bases? Did you remember
You are titrating 20.0mL sample of 0.131 M Ba(OH)2 with 0.350 M HCL.
(a) What volume in mL of HCL solution is needed to reach the equivalence point?
(b) What is the pH after 20.0ml of HCL have been added.
(c) Sketch a titration curve for the above process. Label the axes and the points calculated in (a) and (b) above.
Consider the titration of 36.0 mL of 0.117 M ammonia with 0.0752 M HCl. (See the Acid-Base Table.)
(a) How many mL of HCl are required to reach the equivalence point?5.60 mL(b) What is the pH at the equivalence point? 5.30(c) What is the pH of the solution after the addition of 15.7 mL of acid? (d) What is the pH of the solution after the addition of 82.9 mL of acid?
only need part c and d please
Chapter 14 Solutions
Chemistry: Principles and Reactions
Ch. 14 - Write a net ionic equation for the reaction...Ch. 14 - Write a net ionic equation for the reaction...Ch. 14 - Write a balanced net ionic equation for the...Ch. 14 - Write a balanced net ionic equation for the...Ch. 14 - Calculate K for the reactions in Question 1.Ch. 14 - Calculate K for the reactions in Question 2.Ch. 14 - Prob. 7QAPCh. 14 - Calculate K for the reactions in Question 4.Ch. 14 - Calculate [H+] and pH in a solution in which...Ch. 14 - Calculate [OH-] and pH in a solution in which the...
Ch. 14 - A buffer is prepared by dissolving 0.0250 mol of...Ch. 14 - A buffer is prepared by dissolving 0.062 mol of...Ch. 14 - A buffer solution is prepared by adding 15.00 g of...Ch. 14 - A buffer solution is prepared by adding 5.50 g of...Ch. 14 - A solution with a pH of 9.22 is prepared by adding...Ch. 14 - An aqueous solution of 0.057 M weak acid, HX, has...Ch. 14 - Which of the following would form a buffer if...Ch. 14 - Which of the following would form a buffer if...Ch. 14 - Calculate the pH of a solution prepared by mixing...Ch. 14 - Calculate the pH of a solution prepared by mixing...Ch. 14 - Calculate the pH of a solution prepared by mixing...Ch. 14 - Calculate the pH of a solution prepared by mixing...Ch. 14 - Consider the weak acids in Table 13.2. Which...Ch. 14 - Prob. 24QAPCh. 14 - A sodium hydrogen carbonate-sodium carbonate...Ch. 14 - You want to make a buffer with a pH of 10.00 from...Ch. 14 - Prob. 27QAPCh. 14 - The buffer capacity indicates how much OH- or H+...Ch. 14 - A buffer is made up of 0.300 L each of 0.500 M...Ch. 14 - A buffer is made up of 239 mL of 0.187 M potassium...Ch. 14 - Enough water is added to the buffer in Question 29...Ch. 14 - Enough water is added to the buffer in Question 30...Ch. 14 - A buffer is prepared in which the ratio [ H2PO4...Ch. 14 - A buffer is prepared using the butyric...Ch. 14 - Blood is buffered mainly by the HCO3 H2CO3 buffer...Ch. 14 - There is a buffer system in blood H2PO4 HPO42 that...Ch. 14 - Given three acid-base indicators—methyl orange...Ch. 14 - Given the acid-base indicators in Question 37,...Ch. 14 - Metacresol purple is an indicator that changes...Ch. 14 - Thymolphthalein is an indicator that changes from...Ch. 14 - When 25.00 mL of HNO3 are titrated with Sr(OH)2,...Ch. 14 - A solution of KOH has a pH of 13.29. It requires...Ch. 14 - A solution consisting of 25.00 g NH4Cl in 178 mL...Ch. 14 - A 50.0-mL sample of NaHSO3 is titrated with 22.94...Ch. 14 - A sample of 0.220 M triethylamine, (CH3CH2)3 N, is...Ch. 14 - A 35.00-mL sample of 0.487 M KBrO is titrated with...Ch. 14 - A 0.4000 M solution of nitric acid is used to...Ch. 14 - A 0.2481 M solution of KOH is used to titrate...Ch. 14 - Consider the titration of butyric acid (HBut) with...Ch. 14 - Morphine, C17H19O3N, is a weak base (K b =7.4107)....Ch. 14 - Consider a 10.0% (by mass) solution of...Ch. 14 - A solution is prepared by dissolving 0.350 g of...Ch. 14 - Prob. 53QAPCh. 14 - Ammonia gas is bubbled into 275 mL of water to...Ch. 14 - For an aqueous solution of acetic acid to be...Ch. 14 - Prob. 56QAPCh. 14 - Prob. 57QAPCh. 14 - Water is accidentally added to 350.00 mL of a...Ch. 14 - A solution of an unknown weak base...Ch. 14 - Consider an aqueous solution of HF. The molar heat...Ch. 14 - Each symbol in the box below represents a mole of...Ch. 14 - Use the same symbols as in Question 61 ( = anion,...Ch. 14 - The following is the titration curve for the...Ch. 14 - Prob. 64QAPCh. 14 - Follow the directions of Question 64. Consider two...Ch. 14 - Prob. 66QAPCh. 14 - Indicate whether each of the following statements...Ch. 14 - Prob. 68QAPCh. 14 - Consider the following titration curves. The...Ch. 14 - Consider the titration of HF (K a=6.7104) with...Ch. 14 - The species called glacial acetic acid is 98%...Ch. 14 - Four grams of a monoprotic weak acid are dissolved...Ch. 14 - Prob. 73QAPCh. 14 - Fifty cm3 of 1.000 M nitrous acid is titrated with...Ch. 14 - A diprotic acid, H2B(MM=126g/moL), is determined...Ch. 14 - Prob. 76QAPCh. 14 - Two students were asked to determine the Kb of an...Ch. 14 - How many grams of NaOH must be added to 1.00 L of...Ch. 14 - How many grams of NaF must be added to 70.00 mL of...Ch. 14 - Prob. 80QAP
Knowledge Booster
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.Similar questions
- Consider the titration of HF (K a=6.7104) with NaOH. What is the pH when a third of the acid has been neutralized?arrow_forwardA buffer solution is prepared by adding 5.50 g of ammonium chloride and 0.0188 mol of ammonia to enough water to make 155 mL of solution. (a) What is the pH of the buffer? (b) If enough water is added to double the volume, what is the pH of the solution?arrow_forwardA buffer is prepared by dissolving 0.0250 mol of sodium nitrite, NaNO2, in 250.0 mL of 0.0410 M nitrous acid, HNO2. Assume no volume change after HNO2 is dissolved. Calculate the pH of this buffer.arrow_forward
- A 25.0-mL sample of hydroxylamine is titrated to the equivalence point with 35.8 mL of 0.150 M HCl. a What was the concentration of the original hydroxylamine solution? b What is the pH at the equivalence point? c Which indicators, bromphenol blue, methyl red, or phenolphthalein, should be used to detect the end point of the titration? Why?arrow_forwardYou have a solution of the weak acid HA and add some of the salt NaA to it. What are the major species in the solution? What do you need to know to calculate the pH of the solution, and how would you use this information? How does the pH of the solution of just the HA compare with that of the final mixture? Explain.arrow_forwardWhat is the pH of the solution obtained by titrating 1.30 g of sodium hydrogen sulfate, NaHSO4, dissolved in 50.0 mL of water with 0.175 M sodium hydroxide until the equivalence point is reached? Assume that any volume change due to adding the sodium hydrogen sulfate or to mixing the solutions is negligible.arrow_forward
- Assume you titrate 20.0 mL of 0.11 M NH3 with 0.10 M HCl. (a) What is the pH of the NH3 solution before the titration begins? (b) What is the pH of the equivalence point? (c) What is the pH at the midpoint of the titration? (d) Which indicator would you suggest to detect the equivalence point? (e) Calculate the pH of the solution after adding 5.00, 11.0, 15.0, 20.0, 22.0, and 25.0 mL of the acid. Combine this information with that from (a) through (c) and plot the titration curve.arrow_forwardA 0.1276 g sample of an unknown monoprotic acid was dissolved in 25.0 mL of water and titrated with 0.0633 M NaOH solution. The volume of base required to bring the solution to the equivalence point was 18.4 mL. (a) Calculate the molar mass of the acid. (b) After 10.0 mL of base had been added during the titration, the pH was determined to be 5.87. What is the Ka of the unknown acid? *only need help with barrow_forward3) 2.0 g of NaOH is dissolved in distilled water to prepare 100 mL solution. 20.0 mL of this solution reaches to the equivalence point when 25 mL of an acid solution containing 1.22 g unknown monoprotic weak acid is added. (a) Calculate the molar mass of the unknown acid. (b) After 15.0 mL of NaOH solution had been added during the titration, the pH was determined to be 4.7. What is the Ka of the unknown acid? (NaOH = 40.0 g/mol)arrow_forward
- 2.0 g of NaOH is dissolved in distilled water to prepare 100 mL solution. 20.0 mL of this solution reaches to the equivalence point when 25 mL of an acid solution containing 1.22 monoprotic weak acid is added. (a) Calculate the molar mass of the unknown acid. (b) After 15.0 mL of NaOH solution had been added during the titration, the pH was determined to be 4.7. What is the Ka of the unknown acid? (NaOH = 40.0 g/mol) unknownarrow_forwardA solution NH 3 that contains 78 mL of 0.043 M ammonia, NH 3, is titrated with 0.083 M HCI. The K₁ of ammonia is 1.8×10-5. (a) What volume of 0.083 M HCI would be added to reach the equivalence point? Give the volume in mL. 40.41 mL (b) At the equivalence point, what is the pH of the solution? (Assume that volumes are additive.) 4.56arrow_forward1. Calculate the pH changes during the titration of 0.100 M HCl with 50.00 mL of 0.0500 M KOH when the following volumes of the titrant is added: (a) The volume of the titrant required to reach the equivalence point (b) Select five (5) different volumes of the titrant before the equivalence point. (c) At equivalence point (d) Select five (5) different volumes of the titrant after the equivalence point (e) Plot the titration curve using MS Excel Spreadsheet (f) Plot the 1st order and 2nd order titration curvearrow_forward
arrow_back_ios
SEE MORE QUESTIONS
arrow_forward_ios
Recommended textbooks for you
- General Chemistry - Standalone book (MindTap Cour...ChemistryISBN:9781305580343Author:Steven D. Gammon, Ebbing, Darrell Ebbing, Steven D., Darrell; Gammon, Darrell Ebbing; Steven D. Gammon, Darrell D.; Gammon, Ebbing; Steven D. Gammon; DarrellPublisher:Cengage LearningChemistry: An Atoms First ApproachChemistryISBN:9781305079243Author:Steven S. Zumdahl, Susan A. ZumdahlPublisher:Cengage Learning
- ChemistryChemistryISBN:9781305957404Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCostePublisher:Cengage LearningPrinciples of Modern ChemistryChemistryISBN:9781305079113Author:David W. Oxtoby, H. Pat Gillis, Laurie J. ButlerPublisher:Cengage LearningChemistry: Principles and ReactionsChemistryISBN:9781305079373Author:William L. Masterton, Cecile N. HurleyPublisher:Cengage Learning
General Chemistry - Standalone book (MindTap Cour...
Chemistry
ISBN:9781305580343
Author:Steven D. Gammon, Ebbing, Darrell Ebbing, Steven D., Darrell; Gammon, Darrell Ebbing; Steven D. Gammon, Darrell D.; Gammon, Ebbing; Steven D. Gammon; Darrell
Publisher:Cengage Learning
Chemistry: An Atoms First Approach
Chemistry
ISBN:9781305079243
Author:Steven S. Zumdahl, Susan A. Zumdahl
Publisher:Cengage Learning
Chemistry
Chemistry
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Cengage Learning
Principles of Modern Chemistry
Chemistry
ISBN:9781305079113
Author:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler
Publisher:Cengage Learning
Chemistry: Principles and Reactions
Chemistry
ISBN:9781305079373
Author:William L. Masterton, Cecile N. Hurley
Publisher:Cengage Learning
General Chemistry | Acids & Bases; Author: Ninja Nerd;https://www.youtube.com/watch?v=AOr_5tbgfQ0;License: Standard YouTube License, CC-BY