Question: Which of the following procedures would be best for achieving the following reaction? * CH3 ? CH2-CEC-CH3 Br Br O (A) (i) KOH & heat (ii) CH3C=C-Br (B) (i) KMN04 & heat (ii) CH3C=C(-) Na(+) (iii) excess H20 (C) (i) NBS in CCI4 & heat (ii) CH3C=C(-) Na(+) (D) (i) Mg in ether (ii) CH3C=CBr (iii) excess НЗРО4

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Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
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Chapter1: Chemical Foundations
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Question: Which of the following
procedures would be best for
achieving the following reaction? *
CH3
CH2-C=C-CH3
Br
Br
(A) (i) KOH & heat (ii) CH3C=C-Br
(B) (i) KMNO4 & heat (ii) CH3C=C(-) Na(+) (iii)
excess H20
(C) (i) NBS in CCI4 & heat (ii) CH3C=C(-) Na(+)
(D) (i) Mg in ether (ii) CH3C=CBr (iii) excess
НЗРО4
Question: Which carbenium ion is most
stable *
(CH,),CCH,
(CH,),CCH,CH,
) (CH),CHCHCH,
D) CH,CH,CHCH,CH,
A)
B)
(A)
(B)
(C)
(D)
Transcribed Image Text:Question: Which of the following procedures would be best for achieving the following reaction? * CH3 CH2-C=C-CH3 Br Br (A) (i) KOH & heat (ii) CH3C=C-Br (B) (i) KMNO4 & heat (ii) CH3C=C(-) Na(+) (iii) excess H20 (C) (i) NBS in CCI4 & heat (ii) CH3C=C(-) Na(+) (D) (i) Mg in ether (ii) CH3C=CBr (iii) excess НЗРО4 Question: Which carbenium ion is most stable * (CH,),CCH, (CH,),CCH,CH, ) (CH),CHCHCH, D) CH,CH,CHCH,CH, A) B) (A) (B) (C) (D)
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