20-35 (a) Predict the products, if any, of the following reactions. ascorb (1) LiAlH4 (b) (1) NaCN -COOH CH₂Br (2) H3O+ (2) H3O+, heat (1) SOCI₂ (d) KMnO4, H₂O oct-4-yne (warm, concd.)' (2) AlCl3 COOH

Organic Chemistry
9th Edition
ISBN:9781305080485
Author:John E. McMurry
Publisher:John E. McMurry
Chapter30: Orbitals And Organic Chemistry: Pericyclic Reactions
Section30.SE: Something Extra
Problem 41AP: In light of your answer to Problem 30-40, explain why a mixture of products occurs in the following...
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Predict the products, if any, of the following reactions.
20-35
(a)
ascorbic ac
(1) LiAlH4
-COOH
(2) H3O+
(b)
(1) NaCN
CH₂Br
(2) H3O+, heat
(c)
(1) SOCl2
(d)
KMnO4, H₂O
oct-4-yne
(warm, concd.)
(2) AlCl3
COOH
(e)
CH₂OH
Na2Cr2O7, H2SO4
(f)
Ph
(1) BH3.THF
CH3CH2-CH-COOH
(2) H₁₂O+
Transcribed Image Text:Predict the products, if any, of the following reactions. 20-35 (a) ascorbic ac (1) LiAlH4 -COOH (2) H3O+ (b) (1) NaCN CH₂Br (2) H3O+, heat (c) (1) SOCl2 (d) KMnO4, H₂O oct-4-yne (warm, concd.) (2) AlCl3 COOH (e) CH₂OH Na2Cr2O7, H2SO4 (f) Ph (1) BH3.THF CH3CH2-CH-COOH (2) H₁₂O+
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