Predict the Major product(s) for the following reactions. (10 pts total) Ph Ph mechanism: Show the correct stereochemistry when needed!! mechanism: CI Ph Br H₂S substitution. CH₂ONa DMF A elimination

Predict the Major product(s) for the following reactions. (10 pts total) Ph Ph mechanism: Show the correct stereochemistry when needed!! mechanism: CI Ph Br H₂S substitution. CH₂ONa DMF A elimination

Organic Chemistry

9th Edition

ISBN:9781305080485

Author:John E. McMurry

Publisher:John E. McMurry

Chapter11: Reactions Of Alkyl Halides: Nucleophilic Substitutions And Eliminations

Section11.SE: Something Extra

Problem 27MP

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Concept explainers

Reactions at the Alpha Carbon Atom

The position next to the ketone or aldehyde functional group is termed as alpha position and the reaction which occurs at alpha position is called alpha substitution reaction. In an alpha substitution reaction, the alpha proton atom is substituted by an electrophile by the formation of an enol intermediate or enolate ion intermediate. Most of the carbonyl compounds go through an alpha substitution reaction.

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Predict the Major product(s) for the following reactions. (10 pts total)
Ph
Ph
mechanism:
Show the correct stereochemistry when needed!!
mechanism:
CI
Ph
Br
H₂S
substitution.
CH₂ONa
DMF
Δ
elimination

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