b. ° CH3CH2CCH2CH2 CH₂Br CH3CH2CCH2CH2COOH CH2COOH OH OH C. d. Br COOH 4. Which method would you use to perform these reactions, Grignard carboxylation, nitrile hydrolysis, either, or neither? H&C a. H3C COOH
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Which method would you use to perform these reactions, Grignard carboxylation, nitrile hydrolysis, either, or
neither?
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- Identify the products obtained by the hydrolysis of the given compound. оо | | -COC- Select one: O a. one molecule of dibenzoic acid and one molecule of benzene O b. one molecule of benzene and one molecule of a carboxylic acid O c. two molecules of phenol O d. two molecules of benzoic acid- - " 3. Rank the following carboxylic acids in the order of increasing acidity in an aqueous solution. EXPLAIN. - - - " - A OH - " - - - - - - - O₂N B OH 요 OH HO C H3CO D OHol de C 3. Caffeine is an alkaloid, meaning alkali- or base-like. Circle functional groups in the molecule which would make react as a base. CH3 CH3 a. O b. O 4. Write the equations that account for what happens in the hydrolysis of acetamide O || (CH₂C-NH₂) in (a) acid and in (b) base. woled mode) N I T CH3 H Caffeine custom page 114
- Provide the reagents necessary to carry out the following conversion. credit. OH1. Lit :E 2. HCI Br2, H20 Isunepe enc toss1gwolol ert to rlose 107 (2nion S bonsdmun ed bluorde yisaeesen li ele bensdr CI 18 LICH3 HO 1emonsne+ CI H. (MCPBA) rt ol egete bns ainepssonitail elesrinye biewiols s2ogon9 (niog E E eluoslom e pelom CH3OH catalytic H2SO41. NaOEt CO₂Et 2. H3O+ 3. heat Br H3C CO₂H CO2 H3C CO₂Et The malonic ester synthesis is a carbonyl alkylation reaction. It is used to prepare carboxylic acids from primary alkyl halides, lengthening the carbon chain by two atoms. Thus, the product can be visualized as being a "substituted acetic acid." The reaction consists of three steps: generation of the enolate anion followed by SN2 reaction with a primary alkyl halide, ester hydrolysis under acid conditions, and decarboxylation. Draw curved arrows to show the movement of electrons in this step of the mechanism. Arrow-pushing Instructions 22 CX EtO₂C EtO₂C HOCH2CH3 HOCH2CH3 EtO₂C EtO₂C
- Arrange the following compounds in decreasing order of acidity * |- CICH2CH2CH2COOH Il - CH3CH2CHCICOOH III – CH3CHCICH2COOH III > I> || O I > II > || O I > I| > II III > || >|1. NaOEt CO₂Et 2. H3O+ 3. heat Br H3C H₁C CO₂Et CO₂H CO2 + EtOH The malonic ester synthesis is a carbonyl alkylation reaction. It is used to prepare carboxylic acids from primary alkyl halides, lengthening the carbon chain by two atoms. Thus, the product can be visualized as being a "substituted acetic acid." The reaction consists of three steps: generation of the enolate anion followed by SN2 reaction with a primary alkyl halide, ester hydrolysis under acid conditions, and decarboxylation. Draw curved arrows to show the movement of electrons in this step of the mechanism. Arrow-pushing Instructions EtO₂C X ¯:0: :0: Br: EtO₂C. Br CH3 H3C CH3 CH3 56Chemistry 1. Provide a synthesis of the following carboxylic acids from the given starting materials: LOH а. ? b. CH;CH=CH2 CH;CH,CO,H ? CH;CO,H