Inorganic Chemistry
5th Edition
ISBN: 9780321811059
Author: Gary L. Miessler, Paul J. Fischer, Donald A. Tarr
Publisher: Prentice Hall
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Chapter 8, Problem 8.42P
On the basis of VSEPR, predict the structures of
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5. (a) Deduce the point group of the follo
species :
OH
(i)
HO
HO,
(ü) Co4(Cp)4
(iüi) PF3CI2 (one Cl axial and
one Cl equatorial)
Determine the point group of the following. Consider all square planar
PtCl4²-
Pt(CO)Cl3
cis-Pt(CO)2Cl2
trans-Pt(CO)2Cl2
7.
Please draw the structure of cis-[COB14C12]° and determine its point group.
Chapter 8 Solutions
Inorganic Chemistry
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- Draw the Lewis structure of SF4, determine its molecular geometry and point group, you will find that the molecule is: O Polar but not chiral Non-polar but chiral Polar and chiral O Non-polar and not chiralarrow_forward8. (a) Define chrömophore. Classify according to the type of electronic transitions, giving examples. the chromophoresarrow_forward(a) What does the term diamagnetism mean? (b) How doesa diamagnetic substance respond to a magnetic field?(c) Which of the following ions would you expect to bediamagnetic: N22 -, O22 -, Be22 + , C2-?arrow_forward
- Chemistry How many possible isomers are there of the ion IO2F32-? Sketch these, and indicate the point group of each.arrow_forwardWhat is the main difference between space group and point group symmetries? Which one do we prefer in explaining the physical properties?arrow_forwardE10A.5(b) Assign the following molecules to point groups: (i) HF (ii) IF, (pentagonal bipyramid), (iii) CIF, (T-shaped), (iv) Fe,(CO), (3), (v) cubane, C,H, (vi) tetrafluorocubane, C,H̟F, (4). HO co Fe co F 3 4arrow_forward
- why doesn't F22+ occur (with respect to molecular orbital theory)? illustrate as needed.arrow_forwardSketch the molecular orbital energy level diagram for XeF and deduce its ground-state electron configuration. Is XeF likely to have a shorter bond length than XeF+?arrow_forwardPredict the electron-domain and molecular geometries of (a) BrF3 (b) SF5 + Illustrate how you arrived at your answer.arrow_forward
- use vsepr rules to determine the shapes of each of the following species. then establish their rotation axes and mirror planes and hence identify the point group to which they belong. hint: constructing a molecular model will help (a) phosphine, ph3; (b) the carbonate ion, co3^2-; (c) the sulfate ion, so4^2-; (d) the hexafluorophosphate ion, pf 6-arrow_forward2. For the following molecules, name the idealized VSEPR geometry and assign the point group: (a) GeH₂D₂ (D = deuterium, is distinguishable from hydrogen); (b) AsF5; (c) C₂H₂; (d) [BrF4]; (e) SO₂Cl2.arrow_forward(b) In the construction of the molecular orbital diagram of a polyatomic molecule (SF6), 12 valence electrons are used to occupy 10 MO; account for the origin of the 12 electrons and the 10 MOsarrow_forward
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