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Write the mechanism of the reaction of phenylmethylketone with Br2 in the presence of NaOH.
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- Methyl benzoate was exposed to a nitration test, although it was difficult to see the formation of a fragrant yellow solution. What produced this consequence?write the mechanism for a decarboxylation and state the structural features necessary for a decarboxylation.The substance provided can be prepared by a nucleophilic addition reaction between an aldehydeor ketone and nucleophile. Identify the reactants from which it was prepared. If the substance is an acetal, identify the carbonyl compound and the alcohol; if it is an imine or enamine, identify the carbonyl compound and the amine.
- 3)Write the reaction mechanism by drawing the experimental setups for obtaining benzoin. 7)Write the mechanism of the reaction of phenylmethylketone with Br2 in the presence of NaOH.Why do you wash the dichloromethane solution of your reductive amination product with sodium bicarbonate, rather than dilute aqueous HCl? a) Sodium bicarbonate is a good method of removing aldehydes from organic solvent.b) The amine product will be protonated by acid and remain in the aqueous layer as a salt.c) Sodium bicarbonate transfers the amine starting material into the aqueous layer.d) Sodium bicarbonate reacts with leftover NaBH(OAc)3 and removes it from the mixture.Why is methyl salicylate so easily absorbed through the skin?
- What is the reaction mechanism for formaldehyde and phenol under acidic conditions?Explain why methyl trifluoroacetate, CF3CO2CH3, is more reactive than methyl acetate, CH3CO2CH3, in nucleophilic acyl substitution reactions.Describe the mechanism and name the organic products of hydrolysis of 2,3-epoxybutane in dilute acid.
- Two reactions occur when sodium hydroxide is added to methyl salicylate. One is immediate and one only occurs with reflux over time. What type of reaction occurs immediately and with which functional group on methyl salicylate does it react? What type of reaction occurs with reflux over time and with which functional group on methyl salicylate does it react?On synthesis of esters via nucleophilic acyl substitution: How is excess alcohol eliminated from the crude product? Write the chemical equation involved in the reaction between the excess acid and NaHCO3. Given this, briefly explain why NaHCO3 is preferred over NaOH for the neutralization of excess acid.Write chemical reaction of the epoxide preparation by reacting cis-2-pentene with a peroxycarboxylic acid. peroxycarboxylic acid