Which synthetic route represents the best method for generating the target molecule below? Route A Route B (1) CeH5M gBr/THF Br CH,(CH),CH,0 Na он (2) dil. H+/H,O CH; (CH2),CH2OH Route C Route D HO (1) KOH/ethanole CH;CH,CH,CH-Br (2) CH; CH;CH,CH,Br AIC Route C Route A Route B Route D
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- Question: Predict the mechanism of interactions? C,H;O Na* CH;CH,CHCH; Br H;CHC=CHCH, + H;CH,CHC=CH, ( 81%) C3H;OH (19%)uestion 8 of 8 Step 2 Draw step 2 of the mechanism. OりCX 0 @ H + H,C CI Br .. MacBook Air 吕口 888 F5 F7 FB F10 23 2$ 4 & 2 3 5 7 8 9 W E R. T Y D F K T Z +| +† +t +l *3Drag the appropriate labels to their respective targets. Reset Help sp CH;CH=CH, CH;CCH3 CH;CH2ÓH sp? sp3 CH;C=N CH;CH=NCH3 CH;OCH,CH3
- la t-Bvo-SLoMit egut Ane Part C 2-mathylbutana Drag the appropriate labelis to their recpeotive targets. Labelc oan be uced once, more than once, or not at all H CH3-C-CH,CH; CH, 1 Submit luquwt Anawer Part D cydohaane Drag the appropriate labels to their recpeotive targets. Labelc oan be uced once, more than once, or not at al Help *H H H H -H- -H- H A H H A Submit Iequt AnerWhich is the correct reaction sequence? HO Br OGMU 692578 1 Structure Key: CCMU 692578 1 +şt OCMU 692 @CMU 69250 Si-Cl TBSCI OGMU_692578 1 Bu 4N+F578 692578 O TBAF CMU 692578 THF ? N HO H imidazole MgBr PhMgBr TO N-1 DMF OH H PhCHO H
- 2) Write the major products A- P for each of the following reactions. (70 point) HBr CH,CH,OK* CH;CH,OH t-BuO'K a) Br t-BUOH Br,/ H20 F Br KMNO/ OH Zn 1) 0, 2) Zn/ CH;COOH b) Br NANH, CH,CH,I H. Li NH; -78°C d) A concd. H,SO, L. H,O/ H Br, CCl, excess NaNH, hear NH,0 (2) Asymmetric Synthesis Suggest the mechanism. O O + LDA 11) H CH ₂ LDA 11) Pr - CHO LDA O १ 2 me + + Page: Date: / 오 EWhich of the following reaction sequences will give the meso product? H D DH meso only 1| D, Pd Caco, PhCo, quinoline EOH 21 Na, NH3 (lia), EICH O 1| NANH, NH, THE 2| D, Pd-C, PESO, quinoline O 1| Na. NH, (la), t-BUOH 2) Ha, Pd-C, PECO, quinoline ELOH 1) D, Pd Caco, Pbco, quinoline EOH 21 H, Pd Caco, EIOH
- For structure J, substitute the variable A with a carbonyl group and the variable B with an methyl group The following reaction is carried out What are the reaction conditions synthesize this product? AHCO, BKMnO Structure)+ ??? Na Cro ⒸHSOTHO (E) Dess-Martin periodinane, dichloromethane 1-pentanal A J BWhich disconnection leads to the most reasonable retrosynthesis of the given target molecule 7 O Y=h =7 -37Which of the following represent the reagents in the correct order for the synthesis of the target molecule? 1. CH3CI, ALC!3; 2. H2/Pd; 3. NBS, light А 1. CH;COCI, ALC!3; 2. Zn(Hg), HCl; 3. NBS, light В 1. CH3COCI, AlCl3; 2. Br2, FeBr C 3; 3. H2/Pd 1. CH3CH2CI, AlCl;; 2. Br2, FeBr3; 3. NBS, light Br 1) 2) 3)