Which solution is closest to the pKa? Calculate the pH of the solutions and the change in pH after adding 5.00 mL of 0.10-mol L-1 NaOH. Calculate the pH of the solutions and the change in pH after adding 5.00 mL of 0.10-mol L-1 HCl.
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- Which solution is closest to the pKa?
- Calculate the pH of the solutions and the change in pH after adding 5.00 mL of 0.10-mol L-1 NaOH.
- Calculate the pH of the solutions and the change in pH after adding 5.00 mL of 0.10-mol L-1 HCl.
- Which solution is most resistant to pH change?
- Which solution is least resistant to pH change?
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- 5. From the stock solutions of 1.00-mol L acetic acid and 1.00-mol L of sodium acetate, six solutions were prepared with the acetic acid and acetate concentrations shown in the table below. The pk of acetic acid is 4.756. [Acetic acid). [Acetate). Final volume, Solutio mol L mol L ml A. 0.10 100 0.0000351 100 0.10 0.10 100 0.010 0.010 100 0.10 0.15 100 0.15 0.10 100 -1 Determine the volume of the stock solutions of 1.00-mol Lacetic acid and 1.00-mol L of sodium acetate needed to prepare the solutions. Write your answer in the table below. a. Vol. acetic acid, ml Vol. of acetate, ml Solution A b. Calculate for the initial pH of the solutions and write the pH in the table below. Solution Initial pH A Which solution(s) have the same pH? C.The following data were collected for the reaction 2A + 2B + C 3G+ 4 F Experiment 2 3 4 5 [A] Units of Molarity .00125 .00250 .00125 .00125 .00301 [B] Units of Molarity 00125 .00125 00302 00302 .00100 [C] Units of Molarity 00125 .00125 .00125 00375 .00115 Rate Units M/s 00870 .0174 .0508 .457 a. What is the order with respect to each reactant and what is the overall order for the reaction? Answer this question within the answer box and show your work clearly labeled on the scratch paper. b. Write the rate law for the reaction. Answer this question within the answer box and show your work clearly labeled on the scratch paper. c. What is the value and units for k? Answer this question within the answer box and show your work clearly labeled on the scratch paper. d. Predict the rate for experiment 5, you should give a value and units. Answer this question in the answer box and show your work on the scratch paper labeled clearly.A solution of Na,SO, in water is saturated at 50°C. When a saturated solution of Na,SO, is cooled, crystals of Na,SO4-10H2O separate from the solution Temperature, °C Solubility of Na,SO, g/100g water 49 50 46.7 10 9 If 1000 kg of this solution is cooled to 10°C, the percentage yield obtained is nearly а. 91 b. 90 с. 100 d. 80
- 9. An aqueous solution of sulfuric acid is prepared by mixing a secondary standard of sulfuric acid with deionized water. The aforementioned acid is to be used as a titrant hence its concentration must be accurately determined. To do this, Engr. Polinar, standardized the titrant by titrating two liters of ammonia at 0.90 atm and 30 deg C. From the experiment, 134 mL of the titrant was necessary to neutralize the ammonia. Determine the concentration of the acid in terms of normality? 10. Engr. Forcadela is optimizing a plastic formulation by manipulating the phosgene concentration injected as a gas during the reaction. To obtain credible results, he considered the propensity of phosgene to dissociate into carbon monoxide and chlorine gas at 395 deg C. Performing an experiment at the aforementioned temperature, an equilibrium is reached amongst the species where the total pressure is at 3 atm. If the equilibrium constant expression in terms of concentration for the reaction at 395 deg C…B. Molar Concentration of an Acid Solution Acid type, HA or H,A: HA Unknown No. Balanced equation for neutralization of acid with NaOH. NaOH + HCI = NaCI + Sample 1 Sample 2 Sample 3 1. Volume of acid solution (mL) 25.0 25.0 25.0 2. Buret reading of NaOH, initial (mL) 0.00 0.00 0.00 3. Buret reading of NaOH, final (mL) 26.3 26.0 26.8 26.3 26.0 0.148 4. Volume of NaOH dispensed (mL) 26.8 5. Molar concentration of NAOH (mol/L), Part A 6. Moles of NaOH dispensed (mol) 7. Molar concentration of acid solution (mol/L) 8. Average molar concentration of acid solution (mol/L) Data Analysis, B 9. Standard deviation of molar concentration Data Analysis, C 10. Relative standard deviation of molar concentration (%RSD) Data Analysis, DMolarity of Na2S2O3 (stock solution). 0.100 M Volume of diluted bleach titrated (taken from the volumetric flask). 10ml Initial Burette Reading. 14.80 Final Burette Reading 25.60 Volume of Na2S2O3 used in the titration (mL). 10.80 Moles of Na2S2O3 used in the titration. 1.71 Moles of S2O3–2 used. 1.66 Moles of I2 initially present in titration mixture 0.83 Moles of NaOCl in the diluted bleach titrated. 0.415 Volume of bleach titrated. 1ml Mass of commercial bleaching solution titrated ?
- Ans. 17.15 mg. 54) A 1.000-g sample of a mixture which contains only NaCl and KCl gare a precipitate of AgCl which weighed 2.000 g. What are the percentages of Na and K in the mixture? ins 10 g Ans. 44.77% K; 5.75% Na. 1:J 55. I- can be sernarated from othorMolarity of Na2S2O3 (stock solution). 0.100 M Volume of diluted bleach titrated (taken from the volumetric flask). 10ml Initial Burette Reading. 14.80 Final Burette Reading 25.60 Volume of Na2S2O3 used in the titration (mL). 10.80 Moles of Na2S2O3 used in the titration. 1.71 Moles of S2O3–2 used. 1.66 Moles of I2 initially present in titration mixture 0.83 Moles of NaOCl in the diluted bleach titrated. 0.415 Moles of OCl– in the diluted bleach titrated. ?Molarity of Na2S2O3 (stock solution). 0.100 M Volume of diluted bleach titrated (taken from the volumetric flask). 10ml Initial Burette Reading. 14.80 Final Burette Reading 25.60 Volume of Na2S2O3 used in the titration (mL). 10.80 Moles of Na2S2O3 used in the titration. 1.71 Moles of S2O3–2 used. 1.66 Moles of I2 initially present in titration mixture 0.83 Moles of NaOCl in the diluted bleach titrated. 0.415 Volume of bleach titrated. 1ml Mass of NaOCl in commercial bleach titrated. ?
- Molarity of Na2S2O3 (stock solution). 0.100 M Volume of diluted bleach titrated (taken from the volumetric flask). 10ml Initial Burette Reading. 14.80 Final Burette Reading 25.60 Volume of Na2S2O3 used in the titration (mL). 10.80 Moles of Na2S2O3 used in the titration. 1.71 Moles of S2O3–2 used. 1.66 Moles of I2 initially present in titration mixture 0.83 Moles of NaOCl in the diluted bleach titrated. 0.415 Mass of NaOCl in the diluted bleach titrated. ?The expression for K and K, for the reaction PH,BCI,(s) - PH,(g) + BCI,(g) K = [PH,J[BCI,1/[PH3BCI3] and K, = P(PH,)'p(BCI,) Select one: True False7-11. Limestone consists mainly of the mineral calcite, CaCO3. The carbonate content of 0.541 3 g of powdered limestone was measured by suspending the powder in water, adding 10.00 mL of 1.396 M HCI, and heating to dissolve the solid and expel CO2: CACO3 (s) +2H* → Ca²* +CO,T +H2O Calcium carbonate FM 100.086 The excess acid required 39.96 mL of 0.100 4 M NaOH for complete titration to a phenolphthalein end point. Find the weight percent of calcite in the limestone.