Which of the following reactions affords the desired product as the MAJOR product in each reaction shown? nts A: ) NaOMe, MEOH OH i) Ph Br Ph HO, ) work up B: 1) NaOMe, MEOH OMe i) Ph Br Ph OMe ) work up i) NaOMe, MEOH C: OEt Ph OE! ii) Ph i) work up Br sacza/courses/3464
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- In each reaction box, place the best reagent and conditions from the list provided. 1) Br 2) 3) DEET (the active ingredient in over the counter insect repellant) 4) 5) Answer Bank Mg. Et,0 CH,CH,OH НСООСH, H,CO НСООН NH(CH,CH,),(2 equiv.) Br,, FeBrz CH,COOH HN(CH,CH,), (1 equiv.) NaNH, H,0+ CH,CH,NH, CO, CH,CH, Br SOC, NaCNIn each reaction box, place the best reagent and conditions from the list provided. 1) Br 2) 3) 4) DEET (the active ingredient in over the counter insect repellant) 5) Answer Bank Mg, Et,0 HN(CH, CH, ), (1 equiv.) H,O* CH,COOH CH,CH,NH, CH,CH, Br NH(CH,CH,),(2 cquiv.) НСООСH, H,CO НСООН CH, CH, OH NaCN NaNH, Br,, FeBr, SOCI, CO,biackboard.gwu.edu/webapPps/assessment/feview/review.jsprattempld Select the major product of the reaction below. 1) TIPSCI, Et3N 2) Na 3) 03, then CH3SCH3 4) CH3CH2LI, then H30* 5) Bu4N* F', H2O CI Selected Answer: Он HO Answers: он он он OH OH OH он Select the major product of the reaction below. The answer is there, but please explain step by step.
- The best way to accomplish the following reaction is: CH3 x CH3 (a) Hg(OAc)2, H₂O; NaBH4, HO™ (b) BH3 THF; H₂O₂, HO OH CH3 CH3 (c) H+, H₂O (d) 1. MCPBA; 2. H3O+NBS RO-OR 1) BH3/THF 2) NaOH/ROOR HOBSMO enexerloloyalyitemint-S.tt Jserl H3O*(aq) O 8T-OA Studen t is Purformad the falliwing reaction and atter Com plet ing the work-up Step and isulating be cnde Aridunet iP was detenmined they t The starting matunal Was still Hcsent The student attmped to peaty The Aroduet by columo Chamatagraphy wih Slia gel column and ethyl 94tate as the eluant- The studn't Collected 1o fractiuns and ran g TLC of cnch fraction 4 8 9 10 cunclude about the Separatión ? (whch fractiun s What Can yoy Contained which compund? Are there mixed fract win s?)
- What is the predicted product of the reaction shown? ОТ O II ||| O IV OV OH OH 1. 2. 3. Na2Cr2O7/H2SO4/H2O Оз DMS н || ОН он ОН Ш ее юля О НО IV V ОНFor the reaction below, draw a step-by-Step mechanism (ar rOus men drawa reaction Coordinate diagram as well as mě Struckare of she ransHlon state m for the reacon mechanism for the first Step in the mechanism consist ent with me Hammond Postulate : Но -Br CH gCH2OH + HBr2) mny Starting mater 1al and product. Provide condihons for a reaction when givern I. 3) HH
- Q write mechansim Two reactions: (1) 1., H (1 equiv.) 2. a) LiAlH b) H2O work - up 3. H (final product only ) 1. 2. CH¸ MgBr 3. CH₂OH,H* Gwrite mechansim Two reactions: 0 ② CN 1. HO. OH H+ (1 equiv.) H 2. a) LiAlH4 b) H₂O work-up 3. H+ 1. HO (1 equiv.) H 2. CH3MgBr 3. CH3OH, H+ OH, H+ (final product only) OCH3 (±)122. For the following three step conversion of A to B, the appropriate sequence of reactions is A OH CAREER ENDEAVOUR B CHO (a) MnO₂; (CH₂OH),/p-TSA; PCC (b) PCC; MnO₂; (CH₂OH)₂/p-TSA; (c) PCC; (CH₂OH)₂/p-TSA; Jones' reagent (d) Jones' reagent; (CH₂OH)₂/p-TSA; MnO₂.Он H+ 1) How many intermediaies arc tnore? 2) HOw many transition staies canbe farmd?