Answered: What would have been the effect on the…

Introductory Chemistry: An Active Learning Approach

6th Edition

ISBN:9781305079250

Author:Mark S. Cracolice, Ed Peters

Publisher:Mark S. Cracolice, Ed Peters

Chapter16: Solutions

Section: Chapter Questions

Problem 154E

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The units of parts per million (ppm) and parts per billion (ppb) are commonly used by environmental chemists. In general, 1 ppm means 1 part of solute for every 106 parts of solution. Mathematically, by mass: ppm=gsolutegsolution=mgsolutekgsolution In the case of very dilute aqueous solutions, a concentration of 1.0 ppm is equal to 1.0 g of solute per 1.0 mL, which equals 1.0 g solution. Parts per billion is defined in a similar fashion. Calculate the molarity of each of the following aqueous solutions. a. 5.0 ppb Hg in H2O b. 1.0 ppb CHCl3 in H2O c. 10.0 ppm As in H2O d. 0.10 ppm DDT (C14H9Cl5) in H2O
A student was given a 1.6240-g sample of a mixture of sodium nitrate and sodium chloride and was asked to find the percentage of each compound in the mixture. She dissolved the sample and added a solution that contained an excess of silver nitrate. The silver ion precipitated all of the chloride ion in the mixture as silver chloride. It was filtered, dried, and weighed. Its mass was 2.056g. What was the percentage of each compound in the mixture?
In most of its ionic compounds, cobalt is either Co(II) or Co(III). One such compound, containing chloride ion and waters of hydration, was analyzed, and the following results were obtained. A 0.256-g sample of the compound was dissolved in water, and excess silver nitrate was added. The silver chloride was filtered, dried, and weighed, and it bad a mass of 0.308 g. A second sample of 0.416 g of the compound was dissolved in water, and an excess of sodium hydroxide was added. The hydroxide salt was filtered and heated in a flame, forming cobalt(III) oxide. The mass of cobalt(III) oxide formed was 0.145 g. a. What is the percent composition, by mass, of the compound? b. Assuming the compound contains one cobalt ion per formula unit, what is the formula? c. Write balanced equations for the three reactions described.

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What would have been the effect on the formula weight you calculated for your unknown if some of your unknown had not dissolved prior to the addition of Mg to the solution? (Think of the effect on the recovered mass and how this would alter your calculations.)