What products would you expect from the following reactions. Provide mechanistic rational. OH 1. 2. HO O OH Me Zn(CN)2 HCI, AICI3 OH Me dil. NaOH HO NH2 3. ° CHO Proline OH CHO NH₂ Proline 요 NO,
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- Provide the products and detailed arrow pushing mechanisms for the following reactions: OSIME3 EtN CO.Me 1. base, dilute solution (10mM) 2. NaOH/MEOH-H,0 Acid, heat CO.MePredict the product for the following reaction. Он он excess K,Cr,0,H,SO,H;0Write the products structures and mechanisms CO2H A = N. H (cat.) HO (a) ? NC. CN OMe solvent Ph (i) (ii)
- 2. Predict the structure of the products (A-E) of the following reactions. BugSnH OMe AIBN Toluene, 80 "C OH 1) NaH, CS,, BnBr Ph B HO" 2) BuzSnH, AIBN H Toluene, 80 °C BuşSnH SPh AIBN Toluene, 80 "c 1) LDA, THF, -78 °C then PhSeBr D 2) H202 1) AIBN, SnBu, Me. Br E 2) O, then PPhg(a) MeMgBr (excess) H3O* workup (b) CN NaOH 0 °C (e) Ph. (d) H,O* (cat.) OH Он (e) MeMgBr (excess) HO D,O* workup Predict the product(s) of the following reactions. If you expect no reaction to occur, then you may write “no reaction."Which of the following bases are strong enough to deprotonate CH,CH,CH,C=CH (pK, 25), so that equilibrium favors the products? CH3CH,Li CH3ONA NH3 O H,0 CH;NHNA ONACH,(CO)N(CH3),
- Prediga los productos de las siguientes reacciones. (a) éter sec-butil isopropflico + HBr conc., calor (c) éter di-n-butflico + NaOH conc. caliente (e) etoxibence no + HI conc., calor (b) 2-etoxi-2-metilpentano + HBr conc., calor (d) éter di-n-butllico + Na metálico (1,2-epoxihexano+H*,CH,OH4. Draw structures for products of the following reactions. PaCl, (Bu water tBu PdCI, methanol OH CHCI, NaOH, water Me,N LDA, THE, 0°C BulI (2 moles) Bri THF, -78°C Buli THE, °C Br Pd(OAch THE, 0C MeO5-52 The following syntheses have flaws in them. What is wrong with each? (a) .CH3 .CO2H 1. Cl2, FeCl3 2. KMNO4 CI (b) CІ CI. 1. (CH3)3CCI, AICI3 2. KMNO4, H2O CO2H
- Predict the product for the following reaction. Ш | ОН 0 ОН 1. DIBAH 2. H2O || IV I ОН ОН ОНIdentify the reagent used in the following transformation: OH P Q HO HO P = LIAIH, Q = KMNO, Q = MnO, / CH,Cl, Q = Ag,CO, on celite, PhH (A) (B) P= NABH, /MeOH %3D (C) P=CeCl,.7H,O (D) P= NABH, /CeCl,.7H,0 , / CeCly.7H,O Q = MnO, / CH,Cl,5. Predict all possible products for the following reactions: (a) 1. NAOH, 350 °C 2. H,0* (b) NO 1. NaOH, 80 °C 2. H30* (c) Brz (2 equivalents) FeBr, (d) O,N. CN NH, NO2 (e) NO2 1. NaNH,, NH, (liq.) Br. 2. H,0*