The following reactions involve combinations of pericyclic reactions. Give detailed mechanisms for each transformation. Be sure to illustrate all observed stereochemistry. Identify (by name) the pericyclic reaction(s) in each example. v. vi. + AcO

Organic Chemistry
9th Edition
ISBN:9781305080485
Author:John E. McMurry
Publisher:John E. McMurry
Chapter30: Orbitals And Organic Chemistry: Pericyclic Reactions
Section30.SE: Something Extra
Problem 17MP
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The following reactions involve combinations of
pericyclic reactions. Give detailed mechanisms for each
transformation. Be sure to illustrate all observed
stereochemistry. Identify (by name) the pericyclic
reaction(s) in each example. v.
vi. + ACO
V.
NC
NC
vi.
MeO
OMe
110 °C
OMe
CN
BC
CN
OMe
m
AcO
Transcribed Image Text:The following reactions involve combinations of pericyclic reactions. Give detailed mechanisms for each transformation. Be sure to illustrate all observed stereochemistry. Identify (by name) the pericyclic reaction(s) in each example. v. vi. + ACO V. NC NC vi. MeO OMe 110 °C OMe CN BC CN OMe m AcO
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