The concentration of H2S in wastewater samples was determined by coulometric titration using Kl as mediator and I3 as "titrant". standard concentration Peak area (a.u) (ppm) 50 8354 100 16925 150 25218 200 33584 250 42002 A 50 mL wastewater sample was placed in a coulometric cell, added with excess KI and starch indicator. Electrolysis was carried out at a constant current of 84.6 mA for 386 s to reach the end point of the titration. What is the concentration of H2S in the sample (in ppm)?

Fundamentals Of Analytical Chemistry
9th Edition
ISBN:9781285640686
Author:Skoog
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Chapter22: Bulk Electrolysis: Electrogravimetry And Coulometry
Section: Chapter Questions
Problem 22.28QAP
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The concentration of H2S in wastewater samples was determined by coulometric titration
using Kl as mediator and I3 as "titrant".
standard concentration
Peak area (a.u)
(ppm)
50
8354
100
16925
150
25218
200
33584
250
42002
A 50 ml wastewater sample was placed in a coulometric cell, added with excess Kl and
starch indicator. Electrolysis was carried out at a constant current of 84.6 mA for 386 s to
reach the end point of the titration. What is the concentration of H2S in the sample (in
ppm)?
Transcribed Image Text:The concentration of H2S in wastewater samples was determined by coulometric titration using Kl as mediator and I3 as "titrant". standard concentration Peak area (a.u) (ppm) 50 8354 100 16925 150 25218 200 33584 250 42002 A 50 ml wastewater sample was placed in a coulometric cell, added with excess Kl and starch indicator. Electrolysis was carried out at a constant current of 84.6 mA for 386 s to reach the end point of the titration. What is the concentration of H2S in the sample (in ppm)?
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