Six iron tablets containing FESO-7H,0 were dissolved in 100-ml of 0.1 M HNO; with gentle heating All of the Fe strong oxidizing conditions. After the solution had cooled to room temperature 2.5-ml of 35wt% NH4OH was added The precipitate Fe;0-xH,0 15 convertca that was filtered weighed 0.345 g. Thermogravimetric analysis of the crude product showed a 10.5% weight loss below 150 C. How much iron was in each of the tablets? Report the average mg-Fe per tablet?
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- Six iron tablets containing FeSO4.7H2O were dissolved in 100-ml of 0.1M HNO3 with gentle heating. All of the Fe2+ is converted to Fe3+ by the strong oxidizing conditions. After the solution had cooled to room temperature , 2.5-ml of 35wt% NH4OH was added. The precipitate Fe2O3-xH2O that was filtered weighed 0.345g. Thermogravimetric analysis of the crude product showed a 10.5% weight loss . A. How many waters of hydration were in the precipitate B. How much iron is present in each tablet6. The mercury in a 0.839 g sample was precipitated with an excess paraperiodic acid, H¿IO, 5Hg + 2H,IO, → Hg;(IO,); + 10H The precipitate was filtered, washed free of precipitating agent, dried and weighed, 0.3408 g being recovered. Calculate the percentage of Hg,Cl, in the sample.The arsenic in a 1.010 g sample of a pesticide was converted to H3ASO4 by suitable treatment. The acid was then neutralized, and exactly 40.00 mL of 0.06222M AgNO3 was added to precipitate the arsenic quantitatively as Ag;AsO4. The excess Ag in the filtrate and in the washings from the precipitate was titrated with 10.76 mL of 0.1000MKSCN; the reaction was Ag* + SCN→ AgSCN(s) Calculate the percent AsO3 in the sample.
- A 4.912-g sample of a petroleum product was burnedin a tube furnace, and the SO2produced was collectedin 3% H2O2.Reaction:SO2(g)+H2O2→H2SO4A 25.00-mL portion of 0.00873 M NaOH was introducedinto the solution of H2SO4, following whichthe excess base was back-titrated with 15.17 mL of0.01102 M HCl. Calculate the sulfur concentrationin the sample in parts per million.The following salts were added to a beaker of distilled water: NaCl (NH2)2CO; Ca(NO;)2 Which of the following products will precipitate out of solution? O NH CI O CaCO, FONTHN O O NaCO;The arsenic in a 1.010 g sample of a pesticide was converted to H3AsO4 by suitable treatment. The acid was then neutralized, and exactly 40.00 mL of 0.06222M AgNO3 was added to precipitate the arsenic quantitatively as Ag3AsO4. The excess Ag in the filtrate and in the washings from the precipitate was titrated with 10.76 mL of 0.1000M KSCN; the reaction was Ag+ + SCN-→ AgSCN(s) Calculate the percent AsO3 in the sample.
- 1. A 0.3516 g sample of commercial phosphate detergent was ignited at a heat to destroy the organic matter. The residue was taken up in hot HCI which converted P to H3PO4. The phosphate was precipitated as MGNH4PO4.6H2O by addition of Mg+ followed by aqueous NH3. After being filtered and washed, the precipitate was converted to Mg2P2O7 by ignition at 1000 OC. This residue weighed 0.2161 g. Calculate the percent P (30.974) in the sample? Ans 17.11%A 0.64 g sample containing KCl ( mw = 74.6 ) is dissolved in 50mL of water and titrated to the Ag2CrO4 end point, requiring 26.2 mL of 0.15 M AgNO3 .The %w/w KCl in the sample is ?An aqueous solution of 0.2100 g of a mixture containing potassium cyanide and potassium chloride required 14.56 mL of 0.1000 M silver nitrate to produce a faint permanent turbidity; 30.00 mL more of the silver nitrate was added (an excess) and the precipitate of AgCl and AgCN filtered off from the solution. The filtrate and washings were titrated with 13.06 mL 0.1000 M thiocyanate solution. Calculate the percentages of KCl and KCN in the sample.
- A sample containing BaCl, 2H,0, KCI and inert material weighed 0.8417 g. After heating the sample at 160°C for 45 min, it weighed 0.8076 g. The sample was then dissolved in water and treated with a slight excess of AgNo,. The resulting precipitate was collected and found to weigh 0.5847 g. Calculate the % Bacl,-2H,0 and % KCI in the sample. 3.on in a 1. 200 Sample was precipi toled as the hdroxide and ignited to Ferm Fez0 (0. 352 1 FW= 159-7 lmal). Fnd %Fe (AW : 55-8 glmal)in the Sample. 4 A 2-560 g of impure CCl, Sample was disselved in water and precipitated wii th excess Na Cou Selution. 1F i.245g CaGOu (FW= 12891ml) was obtained, what is the percentage f Cack (FW= mglmal) in the impure Sample? Cu: A 0-21219 sample of an organic Compound was and the Ce, was burned in a stream of oxygen, and the CO2 was Callected in a solution of BalOH), Caleulate the %C in the Sample if o.co06 g of Ba COg was hamedd (FW Ba CO, = 197.34g mol), (AW C=12 glm)КНР (ад) + NаОН (ад)- - NAKHP (aq) + H20 (1) Trial V; (mL) V; (mL) 33.87 45.73 2 A student masses out 1.019 grams of KHP, which is dissolved in 25.00 mL of DI water. This KHP solution is titrated with NAOH, as shown in the equation above. Calculate the molarity of the NaOH solution. RE FS F6 F7 FB F10