Question 15 Given the following proposed mechanism, predict the rate law for the overall reaction. 2 NO2 + Cl2 - 2 NO2CI (Overall reaction) > Mechanism: NO2 + Cl2 NO2CI + CI slow > NO2 + CI → NO2CI fast Rate = k[NO2][Cl2] %3D Rate = k[NO2]?[Cl2] Rate = k[NO2][CI] Rate = k[NO2CI][CI] Rate = k[NO2CI]2

Chemistry: Principles and Practice
3rd Edition
ISBN:9780534420123
Author:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward Mercer
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Chapter13: Chemical Kinetics
Section: Chapter Questions
Problem 13.19QE
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Question 15
Given the following proposed mechanism, predict the rate law for the overall reaction.
2 NO2 + Cl2
2 NO2CI (Overall reaction)
>
Mechanism:
NO2 + Cl2 → NO2CI + CI
slow
NO2 + CI → NO2CI
fast
Rate =
- k[NO2][Cl2]
Rate = k[NO2]?[CI2]
Rate =
- k[NO2][CI]
Rate = k[NO2CI][CI]
Rate = k[NO2CI]2
Transcribed Image Text:Question 15 Given the following proposed mechanism, predict the rate law for the overall reaction. 2 NO2 + Cl2 2 NO2CI (Overall reaction) > Mechanism: NO2 + Cl2 → NO2CI + CI slow NO2 + CI → NO2CI fast Rate = - k[NO2][Cl2] Rate = k[NO2]?[CI2] Rate = - k[NO2][CI] Rate = k[NO2CI][CI] Rate = k[NO2CI]2
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