Q3. For the substitution reactions below, draw out the reactions as shown and answer the following questions for each example: (i) Draw the structure of the unknown product(s) of the reaction. (ii) Identify the nucleophile, electrophile and the leaving group for each step. (iii) Identify each mechanism as SN1 or SN2. (iv) Insert curly arrows to represent the reaction mechanism.
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- Q3. For the substitution reactions below, draw out the reactions as shown and answer the following questions for each example: (i) Draw the structure of the unknown product(s) of the reaction. (ii) Identify the nucleophile, electrophile and the leaving group for each step. (iii) Identify each mechanism as Sn1 or SN2. (iv) Insert curly arrows to represent the reaction mechanism. с. Na Product EQ2. For the reactions below, draw out the reactions as shown and answer the following questions for each example: (i) Identify the nucleophile/electrophile/base/leaving group where applicable (ii) Identify each mechanism as SNl, SN2, E1 or E2. (iii) Insert curly arrows to represent the reaction mechanism. с. CI NaO НО NaCI 95Q2. For the reactions below, draw out the reactions as shown and answer the following questions for each example: (i) Identify the nucleophile/electrophile/base/leaving group where applicable (ii) Identify each mechanism as SŅ1, SN2, E1 or E2. (iii) Insert curly arrows to represent the reaction mechanism. а. Br Nal NaBr + H H CI- NaOH H20 NaCI + + + H H. b.
- don 13. (1) Draw the (E)- and (Z)- isomers of 1,3-dichloro-2-methylbut-2-ene. Using curved arrows, draw (a) an SN2 mechanism and (b) and SN1 mechanism for the substitution reaction shown below. Br ) Draw the organic product(s) formed in the following reactions: 1)0, by 2) Zn. H,0 MShow a sequence of reactions that could be used to synthesize the following compound. You must start from 3-pentanol. No mechanisms needed (HINT: You wil need to bring together more than one of the reactions you have seen in Modules 3 and 4]5. Each of the following may participate in an elimination reaction, under the proper conditions. (a) Circle the alpha (a) carbon. (b) Circle the beta (B) carbon(s). (c) Draw the alkene product(s) that may form, with the new double bond between the a and B positions. (d) If more than one alkene product is possible, circle the most stable (Zaitsev) product. X tx + 3What is the Potential energy diagram for this reaction. Pls draw with as much detail as possible. labels and scale) 2-methylpropan-2-ol ---> 2-methylpropene +H2O Draw the potential energy diagram for the reaction of 2-methylpropan-2-ol ---> 2-methylpropene + H20 (1) Label the structures of the (a) reactants, (b) intermediates, (c) transition states, (d) products, and (e) activation energies (E.) for each step. (2) Which step is the rate-determining step? (3) Identify the electrophile and nucleophile in each step when applicable.
- Substitution and elimination: predict the product Maximum allowed tries per question: Unlimited (5) Draw the major organic product of the reaction. Follow this procedure: determine whether the reaction conditions are acidic or basic; identify the most nucleophilic/basic atom, the electrophilic atom, and the leaving group; predict whether elimination or substitution will occur; and then draw the product. Indicate the stereochemistry at every stereocenter with a single wedged (up), hashed (down), or wavy (a mixture of up and down; either) bond. Launch MarvinJSTM viewer or click image to copy source CI benzene ASubstitution and elimination: predict the product Maximum allowed tries per question: Unlimited (7) Draw the major organic product of the reaction. Follow this procedure: determine whether the reaction conditions are acidic or basic; identify the most nucleophilic/basic atom, the electrophilic atom, and the leaving group; predict whether elimination or substitution will occur; and then draw the product. Indicate the stereochemistry at every stereocenter with a single wedged (up), hashed (down), or wavy (a mixture of up and down; either) bond. Launch MarvinJSTM viewer or click image to copy source CH3 H3C EtONa EtOH Br5a) Draw the product(s) of the reaction shown below. Additionally, identify the nucleophile, electrophile and leaving group.
- Identify the major product of the reaction of an alkene shown below. ||| 1. Hg(OAc)2, H2O 2. NaBH4, NaOH ....... ОН || IV ОН о, ОНited Draw both resonance structures of the most stable carbocation intermediate in the reaction shown. od m... • You do not have to consider stereochemistry. . Do not include anionic counter-ions, e.g., I', in your answer. • Draw one structure per sketcher. Add additional sketchers using the drop-down menu in the bottom Separate resonance structures using the → symbol from the drop-down menu. ● CH4 + ? HBrQ10. For each of the following reactions (a-b), predict whether the substitution is more likely to occur following an Sn1 or Sn2 mechanism; explain your reasoning. Draw the products of each nucleophilic substitution paying particular attention to the stereochemistry of carbon 1. a) Br, CH3 MeOH H3C b) Br NaOH 1 DMF* H3C *N,N-dimethylformamide