Predict the intermediate 1 and final product 2 of this organic reaction: Billsea NaOMe You can draw 1 and 2 in any arrangement you like. 1 H+ 2 work up Note: if either 1 or 2 consists of a pair of enantiomers, just draw one structure using line bonds instead of 3D (dash and wedge) bonds at the chiral center.
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- Draw the structure of the organic product of the reaction between cyclohexene and Q3 then (CH3)2S. • Use the wedge/hash bond tools to indicate stereochemistry where it exists. Separate multiple products using the + sign from the drop-down menu. • In cases where there is more than one answer, just draw one. ● TAYY ChemDoodleⓇ Sn [FPredict the intermediate 1 and final product 2 of this organic reaction: вом You can draw 1 and 2 in any arrangement you like. NaOMe H+ 1 2 work up Note: if either 1 or 2 consists of a pair of enantiomers, just draw one structure using line bonds instead of 3D (dash and wedge) bonds at the chiral center.Draw the organic product(s) of the following reaction. CH3 CH3 H₂C-C-CEC-C-CH3 CH3 CH₂ • You do not have to consider stereochemistry. • Include cationic counter-ions, e.g., Nat in your answer, but draw • If no reaction occurs, draw the organic starting material. Separate multiple products using the + sign from the drop-dow II... ? NaNH, / NH3(I) ChemDoodle SHIF
- Draw a resonance structure, complete with all formal charges and lone (unshared) electron pairs, that shows the resonance interaction of the acetoxy with the para position in phenyl acetate. phenyl acetate ● CH3 • You do not have to consider stereochemistry. • Include all valence lone pairs in your answer. In cases where there is more than one answer, just draw one. Sn [F ?a. Draw and name all of the isomeric products obtainedfrom the monobromination of propane with Br2/light. If halogenation were a completely randomreaction and had an equal probability of occurring atany of the C—H bonds in a molecule, what percentage of each of these monobromo products would beexpected?b. Answer part (a) using 2-methylpropane as the starting material.1. OsO4 2. NaHSO3 In the box below draw the structure of the organic product(s) of this reaction. • Use the wedge/hash bond tools to indicate stereochemistry where it exists. • Show stereochemistry in a meso compound. • If the reaction produces a racemic mixture, draw both stereoisomers. • Draw one structure per sketcher. Add additional sketchers using the drop-down menu in the bottom right corner. • Separate multiple products using the + sign from the drop-down menu. opy aste ChemDoodle >
- Draw the product(s) of the following reactions. CH3(CH₂)7-CEC-(CH₂)7-C Y [*** OH • Consider E/Z stereochemistry of alkenes. • If no reaction occurs, draw the organic starting material. • Draw one structure per sketcher. Add additional sketchers using the drop-down menu in the bottom right corner. Separate multiple products using the + sign from the drop-down menu. H₂C=CH₂ H₂ Lindlar catalyst O $ [ ] كر [References] ChemDoodle Prev5. Provide the major organic products of the following reactions. Use dashed and wedged bonds to represent the configuration of chiral centers. (f) 1. BH3 THF 2. HO', H2O2Cyclic forms of D-glucose: Furanose and Pyranose Recall that aldehyde and alcohol react to form hemiacetal. The O in OH acts as nucleophile, attacking the partially positive C of C=O. The H from the OH of alcohol is transferred to the O of C=O. он R R1 HO, On the other hand, ketone and alcohol also react to form hemiketal. OH R R2 R R1 HO, In glucose the OH in C-4 or C-5 can react with the C=O. If the C-4 OH reacts with the C=O the structure is a furanose (5-membered ring); if C-5 OH the product is a pyranose (6-membered ring). Furanose and pyranose are derived from cyclic ethers furan and pyran. Both furanose and pyranose have two isomers: the alpha and beta (also called anomers). Furan Pyran Furanose and pyranose form of D-glucose (note the numbering of carbon atoms) Furanose (5-membered ring) Alpha Pyranose (6-membered ring) Alpha Beta Beta 1 HO- Но H- Но H- _2 FH- H- OH FHO- H HO. но- H- но- H. Но Но H-4 H_5. FHO- FHO- H OH 6CH2OH H CH,OH CH,OH CH2OH C-1 OH is on the right Alpha-D-…
- Draw the product(s) of the following reactions. H2 Lindlar catalyst CH;CH2-CEC-CH3 Consider E/Z stereochemistry of alkenes. • If no reaction occurs, draw the organic starting material. • Draw one structure per sketcher. Add additional sketchers using the drop-down menu in the bottom right corner. • Separate multiple products using the + sign from the drop-down menu. ChemDoodle >Draw a structural formula for 2,3-dimethylbutanoic acid. • You do not have to consider stereochemistry. • You do not have to explicitly draw H atoms. 0- 8) // CH4 OG It's [ ] در ? ChemDoodleAlkenes undergo an addition reaction with borane in tetrahydrofuran (THF). For the reaction below: BH3 THF (solvent) a Draw the structure of the major organic product. Use the wedge/hash bond tools to indicate stereochemistry where it exists. Use wedge and hash bonds ONLY when needed to show reaction stereochemistry. If the reaction produces a racemic mixture, just draw one stereoisomer. opy aste ChemDoodle