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- Predict the product for the following reaction. || excess H₂ Ni, 100 atm, 150°C IV HO VWhich of the following reactions would succeed?5. (a) The molecule shown below can react with a base, and lose one of the five protons to form an anionic intermediate. Draw this anionic intermediate, and explain why that proton is removed instead of one of the others. CI H Cl -H H H Cl (b) The same molecule can react with Ag", and lose one of the three chlorine atoms to form a cationic intermediate. Draw this cationic intermediate, and explain why that chlorine atom is removed, while neither of the other two are removed. CI H Cl -H H H H CI
- Does the equilibrium lie to the left or to the right in the following reaction: H3CO: + H-Br: 2 H;CO-H + H,CO-H + Br:ONH2 (a) Draw the products of the proton transfer reaction shown here. (b) Draw a free energy diagram for this reaction, indicating whether it is endothermic or exothermic. ? + 1Which of the following is one of several products that could result from the reaction conditions shown? (Note: There are many products that could result under these conditions, however only one of the choices below is one of those possibilities). OH H2SO4 HO, (A) (B) (C) (D) O A ов OC OD
- When the following equation is balanced properly under acidic conditions, what are the coefficients of the species shown?IO3- + H2SO3I2 + SO42-Water appears in the balanced equation as a fill in the blank 5 (reactant, product, neither) with a coefficient of . (Enter 0 for neither.)How many electrons are transferred in this reaction?At pH=7, what will be the structure of the following molecule?For the following reaction identify the acid and the base and predict the position of the equilibrium. e. 2 = acid; = base; Il = acid; = base; favor the right side favor the right side favor the left side favor the left side = acid; =base: acid; Il = base; 11 = acid; 11= base; at equilibrium so equally favors both sides ABCDE O O OB OE C OA
- 2. With crystal clear clarity, provide an explanation for the outcomes of the two reactions below. HOLL CI + он + a) HO b) HO CI + OOH + HO- ■OH HO(a) MeMgBr (excess) H3O* workup (b) CN NaOH 0 °C (e) Ph. (d) H,O* (cat.) OH Он (e) MeMgBr (excess) HO D,O* workup Predict the product(s) of the following reactions. If you expect no reaction to occur, then you may write “no reaction."5. Which one of the following equations would make more products upon addition of acid (H)? Briefly explain. H,SO,(aq) 2 HSO, (aq) + H (aq) HCl(aq) 2H(aq) + Cl'(aq) NH, (aq) + OH(aq) 2 NH;(aq) +H,O(1) 2 Fe,0;(s) 2 2 FeO(s) + O>(g) H(aq) + NH;(1)2 NH, (aq)