O Kinetics and Equilibrium Calculating an equilibrium constant from a heterogeneous equilibrium... Iron(III) oxide and hydrogen react to form iron and water, like this: Fe2O3(s)+3 H2(g) 2 Fe(s)+3 H₂O(g) 3/5 Bi At a certain temperature, a chemist finds that a 3.3 L reaction vessel containing a mixture of iron(III) oxide, hydrogen, iron, and water at equilibrium has the following composition: compound amount Fe2O3 4.10 g H₂ 2.97 g Fe 1.46 g H₂O 2.53 g Calculate the value of the equilibrium constant K for this reaction. Round your answer to 2 significant digits. K₁ = 0 X G

O Kinetics and Equilibrium Calculating an equilibrium constant from a heterogeneous equilibrium... Iron(III) oxide and hydrogen react to form iron and water, like this: Fe2O3(s)+3 H2(g) 2 Fe(s)+3 H₂O(g) 3/5 Bi At a certain temperature, a chemist finds that a 3.3 L reaction vessel containing a mixture of iron(III) oxide, hydrogen, iron, and water at equilibrium has the following composition: compound amount Fe2O3 4.10 g H₂ 2.97 g Fe 1.46 g H₂O 2.53 g Calculate the value of the equilibrium constant K for this reaction. Round your answer to 2 significant digits. K₁ = 0 X G

Chemistry & Chemical Reactivity

9th Edition

ISBN:9781133949640

Author:John C. Kotz, Paul M. Treichel, John Townsend, David Treichel

Publisher:John C. Kotz, Paul M. Treichel, John Townsend, David Treichel

Chapter15: Principles Of Chemical Reactivity: Equilibria

Section: Chapter Questions

Problem 38GQ: At 2300 K the equilibrium constant for the formation of NO(g) is 1.7 103. N2(g) + O2(g) 2 NO(g)...

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At 2300 K the equilibrium constant for the formation of NO(g) is 1.7 103. N2(g) + O2(g) 2 NO(g) (a) Analysis shows that the concentrations of N2 and O2 are both 0.25 M, and that of NO is 0.0042 M under certain conditions. Is the system at equilibrium? (b) If the system is not at equilibrium, in which direction does the reaction proceed? (c) When the system is at equilibrium, what are the equilibrium concentrations?
Chemical Equilibrium I Part 1: You run the chemical reaction C(aq)+D(aq)2E(aq) at 25C. The equilibrium constant Kc for the reaction at this temperature is 2.0. a Write the equilibrium-constant expression for the reaction. b Can you come up with some possible concentrations of C, D, and E that you might observe when the reaction has reached equilibrium at 25C? What are these values? c A student says that only a very limited number of concentrations for C, D, and E are possible at equilibrium. Is this true? State why you think this is true or is not true. d If you start with 1.0 M concentrations of both C and D and allow the reaction to come to equilibrium, would you expect the concentration of C to have decreased to zero? If not, what would you expect for the concentration of C? (An approximate value is fine.) Part 2: Consider the reaction A(aq)F(aq)+G(aq), whose equilibrium constant is 1.0 105 at 20C. For each of the situations described below, indicate whether any reaction occurs. If reaction does occur, then indicate the direction of that reaction and describe how the concentrations of A, B, F, and G change during this reaction. a A(aq) and B(aq) are mixed together in a container. b F(aq) and G(aq) are mixed together in a container. c A(aq) and F(aq) are mixed together in a container. d B(aq) and G(aq) are mixed together in a container. e Just B(aq) is placed into a container. f Just G(aq) is placed into a container. Consider any one of these situations in which a reaction does occur. At equilibrium, does the reaction mixture have appreciably more products than reactants? If not, how would you describe the equilibrium composition of the reaction mixture? How did you arrive at this answer?
A mixture of 0.0565 mol phosphorus pentachloride, PCl5, and 0.0800 mol helium gas, He, was placed in a 1.000-L flask and heated to 250.0C. The phosphorus pentachloride decomposes at this temperature to give phosphorus trichloride, PCl3, and chlorine gas, Cl2. The helium gas is inert. PCl5(g)PCl3(g)+Cl2(g) What is the partial pressure of helium in this equilibrium mixture at 250.0C? At equilibrium, the total pressure is found to be 6.505 atm. What is Kc for the dissociation of PCl5?
For a typical equilibrium problem, the value of K and the initial reaction conditions are given for a specific reaction, and you are asked to calculate the equilibrium concentrations. Many of these calculations involve solving a quadratic or cubic equation. What can you do to avoid solving a quadratic or cubic equation and still come up with reasonable equilibrium concentrations?
The following equilibrium is established in a closed container: C(s)+O2(g)CO2(g)H=393kJmol1 How does the equilibrium shift in response to each of the following stresses? (a) The quantity of solid carbon is increased. (b) A small quantity of water is added, and CO2 dissolves in it. (c) The system is cooled. (d) The volume of the container is increased.
The reaction 2 NO2(g) N2O4(g) has an equilibrium constant, Kc, of 170 at 25 C. If 2.0 103 mol of NO2 is present in a 10.-L. Flask along with 1.5 103 mol of N2O4, is the system at equilibrium? If it is not at equilibrium, does the concentration of NO2 increase or decrease as the system proceeds to equilibrium?
. Consider an equilibrium mixture consisting of H2O(g), CO(g). H2(g), and CO2(g) reacting in a closed vessel according to the equation H2O(g)+CO(g)H2(g)+CO2(g)a. You add more H2O to the flask. How does the new equilibrium concentration of each chemical compare to its origin al equilibrium concentration after equilibrium is re-established? Justify your answer. b. You add more H2to the flask. How does the concentration of each chemical compare to its original concentration after equilibrium is re-established? Justify your answer.
For the equilibrium 2 SO2(g) + O2(g) 2 SO3(g) Kc = 245 (at 1000 K) the equilibrium concentrations are [SO2] = 0.102, [O2] = 0.0132, and [SO3] = 0.184. The concentration of SO2 is suddenly doubled. Show that the forward reaction takes place to reach a new equilibrium.
Consider the following reaction at some temperature: H2O(g)+CO(g)H2(g)+CO2(g)K=2.0 Some molecules of H2O and CO are placed in a 1.0-L container as shown below. When equilibrium is reached, bow many molecules of H2O, CO, H2, and CO2 are present? Do this problem by trial and error-that is, if two molecules of CO react, is this equilibrium; if three molecules of CO react, is this equilibrium; and so on.
The reaction PCl5(g) PCl3(g) + Cl2(g) was examined at 250 C. At equilibrium, [PCl5] = 4.2 105 mol/L, [PCl3] = 1.3 102 mol/L, and [Cl2] = 3.9 103 mol/L. Calculate Kc, for the reaction.
Many sugars undergo a process called mutarotation, in which the sugar molecules interconvert between two isomeric forms, finally reaching an equilibrium between them. This is true for the simple sugar glucose, C6H12O6, which exists in solution in isomeric forms called alpha-glucose and beta-glucose. If a solution of glucose at a certain temperature is analyzed, and it is found that the concentration of alpha-glucose is twice the concentration of beta-glucose, what is the value of K for the interconversion reaction?