Knowing that NH3 is a stronger ligand than H2O that can result in larger "DE" of the split d-orbitals when complexed with a metal cation, such as Cu2+, we can predict that, the absorption wavelength of a [Cu(NH3)6]2+ complex would be lower (higher / lower) than the absorption wavelength of a [Cu(H2O)6]2+ complex. Both absorptions are expected to happen in the range of the EM spectrum.
Knowing that NH3 is a stronger ligand than H2O that can result in larger "DE" of the split d-orbitals when complexed with a metal cation, such as Cu2+, we can predict that, the absorption wavelength of a [Cu(NH3)6]2+ complex would be lower (higher / lower) than the absorption wavelength of a [Cu(H2O)6]2+ complex. Both absorptions are expected to happen in the range of the EM spectrum.
Chemistry: The Molecular Science
5th Edition
ISBN:9781285199047
Author:John W. Moore, Conrad L. Stanitski
Publisher:John W. Moore, Conrad L. Stanitski
Chapter20: Chemistry Of Selected Transition Elements And Coordination Compounds
Section: Chapter Questions
Problem 45QRT
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Atomic Structure
The basic structure of an atom is defined as the component-level of atomic structure of an atom. Precisely speaking an atom consists of three major subatomic particles which are protons, neutrons, and electrons. Many theories have been stated for explaining the structure of an atom.
Shape of the D Orbital
Shapes of orbitals are an approximate representation of boundaries in space for finding electrons occupied in that respective orbital. D orbitals are known to have a clover leaf shape or dumbbell inside where electrons can be found.
Question
![Knowing that NH3 is a stronger ligand than H2O that can result in larger "DE" of the split
d-orbitals when complexed with a metal cation, such as Cu2+, we can predict that, the
absorption wavelength of a [Cu(NH3)6]2+ complex would be lower (higher / lower)
than the absorption wavelength of a [Cu(H2O)6]2+ complex. Both absorptions are
expected to happen in the
range of the EM spectrum.](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2Fec2755b6-7089-4f85-a844-ede57d3c63f1%2F1450b53a-d00e-4be6-95fb-b2b5fea56d59%2Fv522m9t.jpeg&w=3840&q=75)
Transcribed Image Text:Knowing that NH3 is a stronger ligand than H2O that can result in larger "DE" of the split
d-orbitals when complexed with a metal cation, such as Cu2+, we can predict that, the
absorption wavelength of a [Cu(NH3)6]2+ complex would be lower (higher / lower)
than the absorption wavelength of a [Cu(H2O)6]2+ complex. Both absorptions are
expected to happen in the
range of the EM spectrum.
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