ii. Draw the arrows for STEPS 3-4. In STEP 3, the D-glucosyloxy anion reacts with water. In STEP 4, the open chain D-glucose reacts with a hydroxide. What type of reaction is shown in both STEPS 3 and 4? iv.

Organic Chemistry
8th Edition
ISBN:9781305580350
Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
Publisher:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
Chapter8: Haloalkanes, Halogenation, And Radical Reactions
Section8.7: Radical Autoxidation
Problem AQ: Linoleic acid is shown below. What makes this fatty acid particularly susceptible to autoxidation?...
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ONLY ANSWER III-IV

0-H
same as
HO
D-Glucosyloxy anion
STEP 3
HO
D-Glucose, open chain
STEP 4 Or
HO
ene-diolate ion
STEP S
Draw the arrows for STEPS 3-4. In STEP 3, the D-glucosyloxy anion reacts with water. In STEP 4, the
open chain D-glucose reacts with a hydroxide.
ii.
What type of reaction is shown in both STEPS 3 and 4?
iv.
Transcribed Image Text:0-H same as HO D-Glucosyloxy anion STEP 3 HO D-Glucose, open chain STEP 4 Or HO ene-diolate ion STEP S Draw the arrows for STEPS 3-4. In STEP 3, the D-glucosyloxy anion reacts with water. In STEP 4, the open chain D-glucose reacts with a hydroxide. ii. What type of reaction is shown in both STEPS 3 and 4? iv.
0-H
D-Glucose, cyclic
(D-Glucopyranose)
STEP 1
0-H
-0.
0-
D-Glucopyranosyloxy anion
STEP 2 Ring-opening
H-
same as
H-
D-Glucosyloxy anion
STEP 3 H0
i.
Draw the arrows for the transformation of STEPS 1 and 2
ii.
Encircle the HEMIACETAL carbon on D-Glucopyranose
Transcribed Image Text:0-H D-Glucose, cyclic (D-Glucopyranose) STEP 1 0-H -0. 0- D-Glucopyranosyloxy anion STEP 2 Ring-opening H- same as H- D-Glucosyloxy anion STEP 3 H0 i. Draw the arrows for the transformation of STEPS 1 and 2 ii. Encircle the HEMIACETAL carbon on D-Glucopyranose
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