If the Product of this Suzuki reaction is 4-(4-methylphenyl)benzaldehyde, what are the two starting reagents. Please write the name of the structures along with the drawing of the starting reagents.

Organic Chemistry
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ISBN:9781305080485
Author:John E. McMurry
Publisher:John E. McMurry
Chapter12: Structure Determination: Mass Spectrometry And Infrared Spectroscopy
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If the Product of this Suzuki reaction is 4-(4-methylphenyl)benzaldehyde, what are the two starting reagents. Please write the name of the structures along with the drawing of the starting reagents.

4(4'-methylphenyl)-benzaldehyde
107 °C10
H
Transcribed Image Text:4(4'-methylphenyl)-benzaldehyde 107 °C10 H
Suzuki Cross Coupling Reaction
Synthesis of an Unsymmetrical Biaryl via a Suzuki Cross Coupling Reaction'
Experimental Goals:
Perform the cross coupling reaction from two unknown coupling partners and isolate the product.
Determine the structure of the product from its IR and NMR spectra and melting point, and in tum
determine the starting materials.
B(OH)2
Pd(OAc)2, PPH3
аq NazCOs
Br
R'
n-PrOH
R = H, CH3
R' = H, CH3, OCH3
R"
Name
Structure
mp
1-biphenyl-4-yl-ethanone
120-121°C*
CHS
1-biphenyl-4-yl-ethanol
96-98 °C
CH3
biphenyl-4-carbaldehyde
60-63 "C
OH
4-phenyl-benzyl alcohol
104-105 °C"
H.
1-(4"-methyl-biphenyl-4-yl) ethanone
119-120 °C
CH3
OH
1-(4'methyl-biphenyl-4-yl)-ethanol
95-96 "C"
CH3
4(4'-methylphenyl)-benzaldehyde
107 °C"
он
4'-methyl-(biphenyl-4-yl)-methanol
100-101 "C
H.
1-(4"-methoxy-biphenyl-4-yl)-ethanone
Meo
153-154 "C2
CH3
OH
1-(4'-methoxy-biphenyl-4-yl)-ethanol
Meo
120-122 °C
CH3
4'-methoxy-biphenyl-4-carbaldehyde
Meo
105-106 "C4
H.
OH
4'-methoxy-biphenyl-4-yl-methanol
162-163 "C
Meo
Transcribed Image Text:Suzuki Cross Coupling Reaction Synthesis of an Unsymmetrical Biaryl via a Suzuki Cross Coupling Reaction' Experimental Goals: Perform the cross coupling reaction from two unknown coupling partners and isolate the product. Determine the structure of the product from its IR and NMR spectra and melting point, and in tum determine the starting materials. B(OH)2 Pd(OAc)2, PPH3 аq NazCOs Br R' n-PrOH R = H, CH3 R' = H, CH3, OCH3 R" Name Structure mp 1-biphenyl-4-yl-ethanone 120-121°C* CHS 1-biphenyl-4-yl-ethanol 96-98 °C CH3 biphenyl-4-carbaldehyde 60-63 "C OH 4-phenyl-benzyl alcohol 104-105 °C" H. 1-(4"-methyl-biphenyl-4-yl) ethanone 119-120 °C CH3 OH 1-(4'methyl-biphenyl-4-yl)-ethanol 95-96 "C" CH3 4(4'-methylphenyl)-benzaldehyde 107 °C" он 4'-methyl-(biphenyl-4-yl)-methanol 100-101 "C H. 1-(4"-methoxy-biphenyl-4-yl)-ethanone Meo 153-154 "C2 CH3 OH 1-(4'-methoxy-biphenyl-4-yl)-ethanol Meo 120-122 °C CH3 4'-methoxy-biphenyl-4-carbaldehyde Meo 105-106 "C4 H. OH 4'-methoxy-biphenyl-4-yl-methanol 162-163 "C Meo
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