(i) State the boundary conditions that must be satisfied. (1) (ii) Draw rough sketches of three different boxes to illustrate the relationship between the energy separation and the increasing or changing length of the box.

(i) State the boundary conditions that must be satisfied. (1) (ii) Draw rough sketches of three different boxes to illustrate the relationship between the energy separation and the increasing or changing length of the box.

Chemistry

10th Edition

ISBN:9781305957404

Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Chapter1: Chemical Foundations

Section: Chapter Questions

Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...

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Question

(a) Consider the translational motion of a particle in a one-dimensional box of mass m, that is free
to move between x = 0 and x = L:
(i) State the boundary conditions that must be satisfied.
(1)
(ii) Draw rough sketches of three different boxes to illustrate the relationship between the
energy separation and the increasing or changing length of the box.
(3)

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