H H с H2C а) H2C- С—SH KSH SK H2S H2C- H2 NH3 NH2 HC b) HC || HC. + H20 + H30 HC. .CH .CH H H2 C. OK H2 + H20 + КОН H3C H3C d) HC HO. H20 HC + H30 HC. CH HC, CH H

Physical Chemistry
2nd Edition
ISBN:9781133958437
Author:Ball, David W. (david Warren), BAER, Tomas
Publisher:Ball, David W. (david Warren), BAER, Tomas
Chapter14: Rotational And Vibrational Spectroscopy
Section: Chapter Questions
Problem 14.12E
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Question

Identify following reaction is in equilibrium <->, or products favored ->, or reactants favored <-

H2
H
H2
H2C
а)
H2C
C
C-SH
KSH
SK
+
H2S
H2C-
H2
NH3
NH2
HC
HC
b)
H2O
+
+
H30
HC.
CH
HC.
CH
H
H2
H2
.C
OK
+
H20
+
КОН
c)
H3C
H3C
ОН
d)
HC
HO.
+
H2O
HC
+
H30
HC.
.CH
HC.
CH
H
Compound or
Functional Group
pKa
Alcohol
16-17
Water
15.7
Thiols
9-10
Ammonium (ONH4)
Hydrogen Sulfide (H2S)
Carboxylic acid
Hydronium (H3O®)
8-9
7
4-5
-1.5
fo
Transcribed Image Text:H2 H H2 H2C а) H2C C C-SH KSH SK + H2S H2C- H2 NH3 NH2 HC HC b) H2O + + H30 HC. CH HC. CH H H2 H2 .C OK + H20 + КОН c) H3C H3C ОН d) HC HO. + H2O HC + H30 HC. .CH HC. CH H Compound or Functional Group pKa Alcohol 16-17 Water 15.7 Thiols 9-10 Ammonium (ONH4) Hydrogen Sulfide (H2S) Carboxylic acid Hydronium (H3O®) 8-9 7 4-5 -1.5 fo
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ISBN:
9781133958437
Author:
Ball, David W. (david Warren), BAER, Tomas
Publisher:
Wadsworth Cengage Learning,