Draw the organometallic compound that would be produced by each of the following reactions. (a) (b) (c) Li(s) Mg(s). Br Mg(s) ? Ether Br H,C=c=CH THE THE Br Mg(s). ? (d) (e) 1. Li(s), THF CI Ether Br 2. Cul (f) (g) .CI 1. Li(s), THF ? Br Li(s) ? 2. CuI THE
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- 6. What product(s) would you expect to obtain from the following reactions? (a) (c) CH3 NO₂ H₂/Pd KMnO4 H₂O ? ? (b) Br. Br (d) CI. 1. HNO3, H₂SO4 2. Fe, H3O+ OCH 3 ? CH3CH₂CH₂CI AICI3 ?7. Reaction Scheme. NH₂ NH2 or two differnet methods (no same steps/reagents) C5H12N2 1. xs Mel, xs K2CO3 2. Ag2O, H₂O 3. heat Br2, xs NaOH, xs H₂O OHC 1.03 2. DMS CHO3. Predict the product(s) of the following reactions: CH3 CH3CHCH2CH2CO2CH3 2. Hg0* (a) CO2CH2CH3 (b) 1. DIBAH 1. CH3CH2MgBr 2. H30" (c) .COCI CH NH2, ? (d) CO2H CH,OH, ? H2SO4 но CH,CO,COCH,, ? Рyridine (e) CH3 (1) 1. LIAIHA 2. H30 H2C=CHCHCH2CO2CH3 (g) .CONH2 (h) CO2H SOCI2 1. LIAIH, 2. Нао Br CH3 e2016 Cenag Leming
- In each reaction box, place the best reagent and conditions from the list provided. 1) Br 2) 3) DEET 4) (the active ingredient in over the counter insect repellant) 5) Answer Bank SOCI, НСООCH, Br,, FeBr, H,0+ HN(CH,CH,), (1 equiv.) H,CO NH(CH,CH,),(2 equiv.) Mg. Et,0 NaCN CH,CH,NH, CH;CH, Br CO, NANH, НСООН CH,COOH CH,CH,OH6. Match the reagents and condition below with the appropriate reactant.You may list a reagent or condition more than once.Reagents/condition (s) : Cl2; CCl4; FeCl3; uv light; NaOH(aq); HCN(g), (i) But-1-ene : ……………………………………………………………..(ii) 1-chloroethane : ………………………………………………………...5(iii)Butane : ………………………………………………………………………(iv)Methylbenzene : ……………………………………………………………..(v) 2-chloro-2-methylpropane : ………………………………………………….(vi)Propanone : ………………………………………………………………….(vii )Ethanal : …………………………………………………………………….Which conditions will produce the target product in the highest yield? O A) 1. BH3; 2. H₂O₂, NaOH, H₂O B) 1. OsO; 2. S(CH3)2 C) 1. Hg(OAc)₂, H₂O; 2. NaBH4 D) H₂SO4, H₂O A ? B OH racemic mixture
- 6. For each reaction indicate the predominant mechanism: S,1, S,2, E1, or E2. (a) (b) (c) OH H* H* H* ? ? ? A. A OH OH (d) Br (e) .CI NaBr CH,OH DMSO dilute (CH),COK (9) OTs ? OTs (CH),COH Ethanol9. What is the major organic product generated in the reaction sequence below? CI ďa (A) (B) -CI Br 1. K OtBu 2. Cl₂ (C) O ICI ㅎ........ (D)(A) moose the correct product. 1. NaGE, Ero 2. H₂0, A 食。 CO₂ Et -CO₂E7 (B) Coret 31. Choose the best reagents. & 4 (A) 1. LAH; H₂0 2. CHz | 3. H₂0/H+ (B) 1. NaOH, -78% 2. CH31 3. H₂0/H (C) 1. LDA, -78%℃ 2. CH31 3. H₂₂0/H+ 1. Nah, 0°C 2. CH31 3. H₂2₂0/H+* (<) Colt (D)
- 3. Predict the product(s) of the following reactions: (a) .CO2CH2CH3 (b) CH3 1. DIBAH 1. CH3CH2MGB. 2. Hзо* CH3CHCH2CH2C02CH3 2. H30* (d) CO2H COCI CH3NH2 (c) H. 7 CH3OH 7. H2SO4 CH3 H. (f) (e) CH3 1. LIAIH4 2. Нзо* CH3CO2COCH3 Pyridine H2C=CHCHCH2CO2CH3 (h) (g) .CONH2 CO2H SOCI2 1. LIAIH4 2. H20 Br CH3 2016 Cengage Learming wwwwwwWhich reaction sequence will bring about the following transformation? OH 0? 1. Mg. THF 2 co, 3. H,0"(dkute) 1. NaOH, DMSO 2 Naoci ? 1. Mg, THF 2. 8 3. HCrO. HSOlag) 1 Na :=H 20, 3. H0On which do you expect to have a more intense and concentrated “hotspot” of negative charge: methoxideion or bicarbonate ion?