Draw the mechanism for when tert-pentyl alcohol reacts with 3,5-dinitrobenzoyl chloride. Draw another mechanism for when tert-pentyl alcohol reacts with phenyl isocyanate please! 2 different mechanism total please! 3,5-DinitrobenzoatesGently boil 200 mg of 3,5-dinitrobenzoyl chloride and 50 mg of thealcohol for 5 min. Cool the mixture, crush any solid that forms, and add2 mL of 2% Na2CO3 solution. Continue to grind and stir the solid with thesodium carbonate solution (to remove 3,5-dinitrobenzoic acid) for abouta minute, suction filter, and wash the crystals with cold water. Dissolvethe product in about 2.5-3 mL of hot ethanol, add water to the cloudpoint, and allowand allow crystallization to proceed. Wash the 3,5-dinitrobenzoate with water-alcohol and let it dry until next time.NO2NO₂BODOH-CHPOTROH +CICONO₂RONO 2 PhenylurethanesMix 100 mg of anhydrous alcohol and 100 mg of phenylisocyanate (or a-naphthylurethane), and heat on thewater bath for 5 min. Cool, add about 1 mL of ligroin,heat to dissolve the product, perform hot gravityfiltration to remove the small amount of diphenylurea (ifpresent), and cool the filtrate in ice, with scratching toinduce crystallization. Collect the product by suctionfiltration and wash the crystals with cold ligroin and let itdry until next time.ROH + O=C=N0-4RON

Alcohols reacts with acyl chloride to form esters. Alcohols also reacts with phenyl isocyanate to…

Draw the mechanism for when tert-pentyl alcohol reacts with 3,5-dinitrobenzoyl chloride. Draw another mechanism for when tert-pentyl alcohol reacts with phenyl isocyanate please! 2 different mechanism total please!

Draw the mechanism for when tert-pentyl alcohol reacts with 3,5-dinitrobenzoyl chloride. Draw another mechanism for when tert-pentyl alcohol reacts with phenyl isocyanate please! 2 different mechanism total please!

EBK A SMALL SCALE APPROACH TO ORGANIC L

4th Edition

ISBN:9781305446021

Author:Lampman

Publisher:Lampman

Chapter80: Crystallization: Purification Of Solids

Section: Chapter Questions

Problem 4P

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Question

3,5-Dinitrobenzoates
Gently boil 200 mg of 3,5-dinitrobenzoyl chloride and 50 mg of the
alcohol for 5 min. Cool the mixture, crush any solid that forms, and add
2 mL of 2% Na2CO3 solution. Continue to grind and stir the solid with the
sodium carbonate solution (to remove 3,5-dinitrobenzoic acid) for about
a minute, suction filter, and wash the crystals with cold water. Dissolve
the product in about 2.5-3 mL of hot ethanol, add water to the cloud
point, and allow
and allow crystallization to proceed. Wash the 3,5-
dinitrobenzoate with water-alcohol and let it dry until next time.
NO2
NO₂
BODOH-
CHPOTROH +
CICO
NO₂
RO
NO 2

Phenylurethanes
Mix 100 mg of anhydrous alcohol and 100 mg of phenyl
isocyanate (or a-naphthylurethane), and heat on the
water bath for 5 min. Cool, add about 1 mL of ligroin,
heat to dissolve the product, perform hot gravity
filtration to remove the small amount of diphenylurea (if
present), and cool the filtrate in ice, with scratching to
induce crystallization. Collect the product by suction
filtration and wash the crystals with cold ligroin and let it
dry until next time.
ROH + O=C=N
0-4
RO
N

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