Determine the pH of (a) A 0.10 M CH3COOH solution (ICE) (b) A solution that is 0.10 M CH3COOH and 0.10 M CH3COONa. Ka for CH3COOH = 1.8 X 10-5.
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Determine the pH of
(a) A 0.10 M CH3COOH solution (ICE)
(b) A solution that is 0.10 M CH3COOH and 0.10 M CH3COONa. Ka for CH3COOH = 1.8 X 10-5.
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- (vi) HCN is a weak acid with a Ka of 4.9 x 10-10. Write an equilibrium expression for this process and calculate the pH for a 0.4 mol L-1 solution of HCN.The major component of vinegar is acetic acid, CH3COOH. Its Ka is 1.8 × 10-5 . One student used 1.000 M NaOH to titrate 25.00 mL vinegar. At the end point, 21.82 mL NaOH was used. (a) What is the concentration of CH3COOH in vinegar? (b) What is the pH of the solution at the end point? (c) What indicator(s) the student should use in this titration? Explain8. (a) HA(aq) is a weak acid with a dissociation constant, Ka, of 8.8 x 10−12. What is the pH of a 0.022 M solution of A−(aq)? The temperature is 25 ◦C. (b) For the reaction A(g) =A(l), the equilibrium constant is 0.666 at 25.0 ◦C and 0.222 at 75.0 ◦C. Making the approximation that the entropy and enthalpy changes of this reaction do not change with temperature, at what temperature will the equilibrium constant be equal to 0.777?
- 24. A solution of volume 0.500 L contains 1.68 g NH3 and 4.05 g (NH4)2SO4. (a) What is the pH of this solution? (b) If 0.88 g NaOH is added to the solution, what will be the pH? (c) How many milliliters of 12 M HCl must be added to 0.500 L of the original solution to change its pH to 9.00?650.0 mL of HBr gas at 21.0 °C and 1025 mm Hg is absorbed completely into a solution that was created by mixing 7.147 g of Na2CO3 and 250.0 g of water. (a) What is the pH of the solution? (b) What is the freezing point of the solution?(f) Calculate the pH of the following solutions: (i) A 0.045 M solution of sulphuric acid. (ii) A solution containing 0.4 g sodium hydroxide in 100 cm³ water. (iii) Given the Ka value for CH3COOH is 1.8 x 10-5, calculate the pH of the acid. The initial concentration of the acid is 0.2 M
- (7) Calculate the pH of each of the following solutions: (a) 0.1000M Propanoic acid( HC H O,,K=1.3x105) (b) 0.1000M sodium propanoate (Na C HỎ) (c) 0.1000M HC₂H₂O, and 0.1000M Nа С¸¸0₂ 3 5 52 (d) After 0.020 mol of HCl is added to 1.00 L solution of (a) and (b) above. (e) After 0.020 mol of NaOH is added to 1.00 L solution of (a) and (b) above.4. Complete neutralization of 10 mL of hydrochloric acid solution by NaOH 0.1 N in the presence of phenol phthalein until the appearance of purple color (pHf= 9) 15 mL of NaOH is consumed. (a) What is the concentration of hydrochloric acid? (b) Calculate the indicator error.A 0.018 M solution of salicylic acid, HOC6H4CO2H, has the same pH as 0.0038 M HNO3solution. (a) Write an equation for the ionization of salicylic acid in aqueous solution. (Assume only the –CO2H portion of the molecule ionizes.) (b) What is the pH of solution containing 0.018 M salicylic acid? (c) Calculate the Ka of salicylic acid.
- Which of the following pairs of solution would you use to prepare a buffer with pH = 7.45? (A) Acetic acid + sodium acetate; (CH3CO2H has Ka = 1.8 x 10–5) (B) Sodium dihydrogen phosphate + sodium hydrogen phosphate; (H2PO4– has Ka = 6.2 x 10–8) (C) Ammonium chloride + ammonia; (NH3 has Kb = 1.8 x 10–5) (D) Sodium hydrogen carbonate + sodium carbonate; (HCO3– has Ka = 5.6 x 10–11)Given that Ka's for hydrofluoric acid (HF) and boric acid (H3BO3) are 6.3 x 10-4 and 5.4 x 10-10, respectively, calculate the pH of the following solutions: (a) The mixture from adding 50 mL 0.2 M HF to 50 mL 0.5 M sodium borate (NaH2BO3). (b) The mixture from adding an additional 150 mL 0.2 M HF to the solution in (a), i.e., a total of 200 mL 0.2 M HF was added to 50 mL 0.5 M NaH2BO3.A buffer is made with sodium acetate (CH3COONa) andacetic acid (CH3COOH); the Ka for acetic acid is 1.80 x 10-5.The pH of the buffer is 3.98. What is the ratio of the equilibriumconcentration of sodium acetate to that of acetic acid?(a) -0.760 (b) 0.174 (c) 0.840 (d) 5.75 (e) Not enough informationis given to answer this question.