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- a) Complete the following reactions: (i) H3C-C-Ci + H2O A + B (ii) HO H;C. CH3 SOCI, с + D + so, (iii) H;O* HCN E F CH;CH, `CH;3 (iv) CH;CH,CH,CH,CH,Br + NH3 G + H excess(b) Write the mechanism for the formation of products in following reaction. Clearly show the intermediates in the reaction. Which product is a kinetically controlled and which one is the thermodynamically controlled product? CH3 CI. CI. A½O3, HCI H Ph-C=C-CH3 Ph CH3 Ph H.(b) Predict the suitable solvent (H2O or CH3COCH:) to increase the reaction of bromopropane (CH3CH2CH2B1) with sodium hydroxide (NaOH). Two reactions are shown below: NaOH, 55 °C CH;CH,CH,Br CH;CH,CH,OH + + NaBr H,O (i) NaOH, 55 °C CH;CH,CH,Br CH;CH,CH,OH + NaBr (ii) H,C- CH3
- b) Refer to the following equation to answer Q3b (i), (ii) and (iii). CH3 H,SO, Н—с—он C-CH3 ? + H2O Но- ČH3 (i) Determine the product of the above reaction. (ii) Name the above reaction. (iii) Propose the mechanism for the above reaction.It is not uncommon for organic chemists to prepare acetals by an exchange-type process known as transacetalization. Predict the product(s) and show the mechanism for the transacetalization reactions below.The following sequence of steps converts (R)-2-octanol to (S)-2-octanol. Propose structural formulas for intermediates A and B, specify the configuration of each, and account for the inversion of configuration in this sequence.
- Nonconjugated , -unsaturated ketones, such as 3-cyclohexenone, are in an acid-catalyzed equilibrium with their conjugated , -unsaturated isomers. Propose a mechanism for this isomerization.Please provide a step by step list explaining the mechanism for the reactionsPlease give the main substitution product for each of the following reactions, and indicate the dominant mechanism: (a) 1-bromopropane + NaOCH3 → (b) 3-bromo-3-methylpentane + NaOC2H5 →
- Suggest mechanisms for the following reactions, both of which involve radical intermediates: (b) (c) Br. MeO MeO CO₂Et N-NO Bu3SnH, AIBN heat hv HO `N MeO MeO NH CO₂EtAcid-catalyzed dehydration of neopentyl alcohol, (CH3)3CCH2OH, yields 2-methyl-2- butene as the major product. Outline a mechanism showing all steps in its formation.(c) Provide the mechanism for the following reactions : NaOMe (i) МеОН OH 22 °C, 4 hr СНО КОН (ii) + MeOH write the mechanisms
