BaCO3 = Ba-* + CO3² reaction was given. It is known that the carbonate anion is hydrolyzed in CO3 + H;O = HCO; + OH Kb1 [HCO3][0H¯] and HCO; + H20 = H;CO3 - OH Kb2 [H2CO3][OH¯] form. [HCO] Since Kg1 = 1.44x10-7, K2 = 4.7x1011 and KepBaco3 = 5.1x10-9, calculate the solubility of %3D BaCO; salt at pH = 8 and 12 depending on the pH value.

Introduction to General, Organic and Biochemistry
11th Edition
ISBN:9781285869759
Author:Frederick A. Bettelheim, William H. Brown, Mary K. Campbell, Shawn O. Farrell, Omar Torres
Publisher:Frederick A. Bettelheim, William H. Brown, Mary K. Campbell, Shawn O. Farrell, Omar Torres
Chapter4: Chemical Reactions
Section: Chapter Questions
Problem 4.79P
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BaCO3 - Ba2+ + CO3? reaction was given.
It is known that the carbonate anion is hydrolyzed in
[HCO ][OH]
[co? ]
CO3- + H20 = HCO; + OH Kb1
and
[H2CO3][OH¯]
[HCO3]
HCO; + H2O = H;CO3 - OH- Kb2 =
form.
Since Ka1 = 1.44x10-7, Ką2 = 4.7x10-11 and KspBaco3 = 5.1x10-9, calculate the solubility of
BaCO; salt at pH = 8 and 12 depending on the pH value.
Transcribed Image Text:BaCO3 - Ba2+ + CO3? reaction was given. It is known that the carbonate anion is hydrolyzed in [HCO ][OH] [co? ] CO3- + H20 = HCO; + OH Kb1 and [H2CO3][OH¯] [HCO3] HCO; + H2O = H;CO3 - OH- Kb2 = form. Since Ka1 = 1.44x10-7, Ką2 = 4.7x10-11 and KspBaco3 = 5.1x10-9, calculate the solubility of BaCO; salt at pH = 8 and 12 depending on the pH value.
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