An atomic absorption spectroscopy analysis provided the following data for theanalysis of Cu in a river sample:SampleAbsorbanceBlank0.00021.00 mg/L0.14313.00 mg/L0.37825.00 mg/L0.58097.00 mg/L0.7920River water0.65408.5.1 Use a suitable scale and plot a calibration curve to determine theconcentration of Cu (mg/L) in the river sample.(5)

Step 1:Absorbance is the dependent variable; it is placed on y-axis.Concentration is independent…

Answered: An atomic absorption spectroscopy…

Fundamentals Of Analytical Chemistry

9th Edition

ISBN:9781285640686

Author:Skoog

Publisher:Skoog

Chapter28: Atomic Spectroscopy

Section: Chapter Questions

Problem 28.6QAP

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A company is producing a powder which can be reconstituted as a healthy drink for the elderly. Analysis of the powder for calcium involved using the following procedure. 4 g of powder was reconstituted to 150 ml with water. Thirty ml of 24 % TCA was added to 30 ml of this solution. The mixture was allowed to stand for 15 mins and then filtered. The filtrate was analysed for calcium using atomic absorption spectroscopy. From the standard curve it was found that the reading for the analysed sample was 24mg/litre. Calculate the concentration of calcium in the powder (mg/kg).
(a) A sample of body serum is to be analysed for sodium by flame emission spectroscopy. 1.00cm3 aliquot of serum was pipetted into each of two 50.0 cm3 volumetric flasks. The firstflask was diluted to volume with deionised water. The absorbance of this first solution was0.350. To the second flask 10.0 cm3 of a 25.0 ppm sodium standard was added and theflask made up to volume with deionised water. The absorbance of this second solution was0.720.(i) Calculate the concentration of the sodium in the body serum in mg dm–3
Explain why an internal standard is required during sample preparation in quantitative analysis when using atomic spectroscopy?
Prepare a calibration curve to determine the Pb content in a well water sample using atomic absorption spectrophotometry; the following data were recorded: % T 100 75.2 56.6 42.5 31.9 24.6 13.8 ppm Pb 0 0.2 0.4 0.6 0.8 1.0 1.4 A 50 mL aliquot of well water is taken and diluted twice, the% T reading is taken and a value of 40.6% is recorded. Calculate the ppm of Pb in the well water.
Define mass spectroscopy and the underlying principle/background of its method for characterizing samples.
Flame Atomic Absorption Spectroscopy (FAAS) method is selected due to its wide applicability for metal ion analysis in drinking water samples. Provide appropriate discussion to determine the concentration of selected heavy metals (Cu and Cr) in the unknown tap water sample.
7 of 10 > Atomic absorption spectroscopy was used to determine the amount of aluminum in a sample of sunscreen. A blank solution was measured seven times to determine the detection and quantitation limits of the spectrometer. The blank readings were: 0.0073, 0.0082, 0.0110, 0.0101, 0.0102, 0.0098, and 0.0090 AU. Determine the signal at the detection limit and the signal at the limit of quantitation for this method. signal detection limit: signal limit of quantitation: hulu étv 14
A sample of water from the North Sea was analysed by ion-chromatography and the sulfate concentration was determined to be 2960 mg/L. A sample of formation water from a reservoir near Shetland was analysed by atomic emission spectroscopy and thestrontium concentration was determined to be 770 mg/L. If the Ksp value for strontium sulfate is 3. 44x10-7 mo? L2 predict whether precipitation should occur if 500 ml of the seawater is mixed with 500 ml of the formation water.
A sample of body serum is to be analysed for sodium by flame emission spectroscopy. 1.00cm' aliquot of serum was pipetted into each of two 50.0cm' volumetric flasks. The first flask was diluted to volume with deionised water. The absorbance of this first solution was0.350. To the second flask 10.0 cm' of a 25.0 ppm sodium standard was added and the flask made up to volume with deionised water. The absorbance of this second solution was 0.720.(i) Calculate the concentration of the sodium in the body serum in mg dm-3.
Seawater was spiked with phosphate to achieve a quantifiable range of phosphate concentrations by spectroscopy. What components of the spectrophotometer or sample preparation could be changed that would improve detection limits?
(a) Three components in a mixture have varying distribution constants between the mobile phase and the stationary phase. One of the components has a very high distribution constant. Would this component likely elute first or last and how would you design an experiment or modify the components of the separation to make it perform in the opposite manner? (b) One way to dramatically increase the sensitivity of a quadrupole mass spectrometer is to use a technique called selected ion monitoring (SIM). Explain how this technique works and why it improves sensitivity. Explain what dwell time means. Be sure to draw a diagram and describe how this analysis scheme works. Also, is there a compromise between a wide range of masses scanned and SIM? Explain in easy details.
Exactly 5.00 mL aliquots of a solution containing analyte X were transferred into 50.00-mL volumetric flasks and the pH of the solution is adjusted to 9.0. The following volumes of a standard solution containing 2.00 µg/mL of X were then added into each flask and the mixture was diluted to volume: 0.000, 0.500, 1.00, 1.50 and 2.00 mL. The fluorescence of each of these solutions was measured with a fluorometer, and the following values were obtained: 3.26, 4.80, 6.42, 8.02 and 9.56, respectively. ii. Using relevant functions in Excel, derive a least-squares equation for the data, and use the parameters of this equation to find the concentration of the phenobarbital in the unknown solution.

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