ACTIVITY 6.2.5 Supply the missing product in the reactions by drawing its structure and giving its name 1. 'CHO H- -O- Weak axidizing 3 HO agent HO H- OH CHOH DGalactese 'CHO 2 H- OH 2.
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- 5..8. What is the expected major for the following reaction ?Addition of oxygen nucleophiles: ROH add'n w/acid cat.; prep. of stable acetals (18.13) aldehydes/ketones react w/ROH to form unstable/unisolable hemiacetals aldehydes/ketones react w/2 equiv. of ROH and acid catalyst to afford stable/isolable acetals, with a hemiacetal as a mechanistic intermediate Sample rxn: Propose the mechanism: CH3 2:0 H H* (cat.) OCH 3 OCH 3 an acetal (NOT an ether or "diether") + (chap. 17 & 18) H Note: acetal carbon has same oxid. state as C=O carbon 117.23 Use mechanisms to predict the products of the fol- 1) LIAIH, Et₂O NH 2) NaOH, H₂O
- (30) Br: route Please provi de complete multI Step Synthetic vapen Include Intermeda te steps (No Mechanism or transition states) include reagents6. (20 points) Complete the following reactions. No reaction is a possible answer. а) Br Mg 1) CO2 (R) 2) H+, Н2о CH3 b) (CH3)2CULI ČH3 c) diethylamine H3C CH3 (5 points) What hydrolysis products are formed when the following compound is treated with aqueous acid? No reaction is an acceptable answer. CH3 H3CO H20, H+4.7 Aniline can be synthesized from benzene by using correct synthetic schemes. Choose one scheme that can be used to produce aniline from benzene from the given options A. B. C. NO₂ H₂SO4 D. HNO3 H₂SO4 1. SnCl,, HO* 2. HO HNO3 H₂SO4 Product Product Product Product 1. SnCl, HgO* 2. HO H₂/Pd Ethanol HNO3 H₂SO4 1. NaOH, 300 °C 2. H₂O* Aniline Aniline Aniline Aniline
- 3.32 In each of the following cases, identify whether the reagent shown is suitable to accomplish the task described. Explain why or why not: a. To protonate b. C. > Answer To protonate To protonate d. To protonate .N. using using H₂O I-Z using H₂O using H₂O2) Complete the following: Stereochemistry and regiochemistry may be important. (10 pts) a) MeO₂C b) c) d) e) type type type type type NH, a) b) CO₂Et a) b) MeO₂C a) b) c) Acetoacetic ester synthesis a) NaH, THF b) BnBr, THF c) aq, NaOH; aq. HCI; D Aldol Condensation IZ CO₂Et CO₂Et O CO₂H CHO f) g) h) i) j) type type type O type H type a) CO,Et b) c) tor Br CO₂H Selective Catalytic Hydrogenation -Não ol EtOH OEt O a) SOCI2, D b) p-MeC6H4OH AICI3, C6H5NO2₂ OH HO H7:39 AM Fri Nov 6 * 39% A learn-us-east-1-prod-fleet01-xythos.s3.amazonaws.com Consider each of the following worded reactions. Write a chemical equation for, each ne and categorite each one rynthesis, decomposchion, combustion, ingle as a replacement or double replacement reaction. Cligu'd) Proponoe burns in the frezence of gaseous ory gen to roduce gaseous carbon dibxrde & liqui'd warter. Solid cal cibm carbonate roducing solid calcium oxide is heated to a and gase ouf carbon high temp. ☺ Copper Ci) sulfate reacts with an iron nail coating it with Copper Solid baking soda (sodlim bicarboncate) reacts with vinegar to grodvee carbon diberde, water and sodium acetate (agueous). O Hqueous lead CI) nitrate reacts with gotassiom sulfide Caqueous) to produce a grecipitate of lead C1) sculfide and agueous potaslom dioxide. 206'd and poodu ang aqueous iron (") sulfate. * All equations must be balanced G state symbolo must be symbols an nitrote. ed equ ons for Activ included
- © (7) (8) (9) CHO CHO Br₂ ACOH + HCHO ( con. NaOH OH™ .CI AICI 3 ) ( ) )+ HCOO CH₂MgBr ( (a-halogenation) (Crossed cannizzaro reaction) (Crossed aldol reaction) )A 8.4 What is the product of this reaction? hint-also consider the stereochemistry mCPBA5.2 (a) Draw curved arrows to represent the flow of electrons in the intermediate product. (b) Draw the product resulting from the arrow movement in the intermediate product. Do not show the formation of any by-products. Oo OH `CI Intermediate Product Product