a. The aromatics are analysed and found to contain 33.2 mol% pseudocumene, 1 mol% diphenyl, 20 mol% benzene and 12.3 mol% toluene. What is the mole fraction of xylene in the aromatics stream?

Introduction to Chemical Engineering Thermodynamics
8th Edition
ISBN:9781259696527
Author:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Publisher:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Chapter1: Introduction
Section: Chapter Questions
Problem 1.1P
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Question

a. The aromatics are analysed and found to contain 33.2 mol% pseudocumene, 1 mol% diphenyl, 20 mol% benzene and 12.3 mol% toluene. What is the mole fraction of xylene in the aromatics stream?

b. Determine the pressure (in bar) of ethylene glycol at 250 K if it has a density of 50 kg/m3. Use the van der Waals equation of state. Answer in 2 decimal places.

Hydrodealkylation
is a process in which side
chain alkyl groups (like methyl) are removed from
aromatics by reaction with hydrogen. The
following reactions take place in the reactor:
E1
C6H5CH3 + H₂ → C6H6 + CH4
82
C6H4 (CH3)2 + H₂ → C6H5CH3 + CH4
€3
C6H3(CH3)3 + H₂ → C6H4(CH3)2 + CH4
In addition, an unwanted side reaction occurs, in
which benzene dimerizes to form diphenyl
[C6H5C6H5].
2 C₂H₂
C6H5C6H5 + H₂
A process stream containing 5 mol % benzene
[C6H6], 20 mol% toluene [C6H5CH3³], 35 mol%
xylene [C6H4(CH3)2], and 40 mol%
pseudocumene [C6H3(CH3)3] is fed to a
hydrodealkylation plant. This process stream is
mixed with hydrogen gas in 5:1 gas-aromatics
ratio before being fed to the reactor. A condenser
separates hydrogen and methane from the other
reactor products (lumped as aromatics).
Feed
? B
? T
? X
? P
84
Reactor
Hydrogen Gas
? H₂
Light Gases
? H₂
? M
Condenser
Aromatics
? B
?T
? X
?P
?D
Transcribed Image Text:Hydrodealkylation is a process in which side chain alkyl groups (like methyl) are removed from aromatics by reaction with hydrogen. The following reactions take place in the reactor: E1 C6H5CH3 + H₂ → C6H6 + CH4 82 C6H4 (CH3)2 + H₂ → C6H5CH3 + CH4 €3 C6H3(CH3)3 + H₂ → C6H4(CH3)2 + CH4 In addition, an unwanted side reaction occurs, in which benzene dimerizes to form diphenyl [C6H5C6H5]. 2 C₂H₂ C6H5C6H5 + H₂ A process stream containing 5 mol % benzene [C6H6], 20 mol% toluene [C6H5CH3³], 35 mol% xylene [C6H4(CH3)2], and 40 mol% pseudocumene [C6H3(CH3)3] is fed to a hydrodealkylation plant. This process stream is mixed with hydrogen gas in 5:1 gas-aromatics ratio before being fed to the reactor. A condenser separates hydrogen and methane from the other reactor products (lumped as aromatics). Feed ? B ? T ? X ? P 84 Reactor Hydrogen Gas ? H₂ Light Gases ? H₂ ? M Condenser Aromatics ? B ?T ? X ?P ?D
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