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- g. Sn1 SN2 E1 Е2 CH3 H3C- -CH3 ČH3 + HI Product(s) of reaction g.Which starting materlal will result In this product when these reagents are used? Click on a letter A through D to answer. 1. NANH2 2. CH3CH2B 3. H2, Lindlar's cat. A. С. D. B.Complete the following reactions by providing any missing components. Provide all products formed and label as major/ minor when necessary. a. b. c. majc whe 1. Complete the following reactions by providing any missing components. Provide all products formed and label as major/minor when necessary. a. b. HNO3 H₂SO excess K2Cr2O7 OH H2SO4 Цон H₂SO H Tollen's Reagent ortho product H₂ Pd-C CH3OH H2SO4
- 3 Complete the following table, filling in the missing major product(s), reagents/conditions, starting material and/or name of the reaction as shown in the example. Starting Materials Ex. b. C. d. dj f. 09 ỌCH3 CH3 CH3 NO₂ Reagents H₂O H* (cat.) C1₂ AICI3 HNO3 H₂SO4 SO3 H₂SO4 Br₂ FeBr3 AICI3 Major Product(s) O= OH2. Provide reagents/conditions to accomplish the following syntheses. More than one step is required in some cases. a. b. Br Br HO₂C -NH₂ NH₂2. Provide reagents/conditions to accomplish the following syntheses. More than one step is required in some cases. a. b. d. Br Br NH₂ HO₂C -NH₂ NH₂ HN- + N(CH3)3
- III. Draw the major products or required reagents for the following reaction sequences. Be certain to indicate stereochemistry where it is relevant. A. B. C. EtO. FO N Bz Ph CH3 OEt AICI3 NaOCH 3 CH₂OH, A 1) NaOEt 2) Br2, CH3COOH 1) NaBH4 2) H3O+ workup H3O+, APredict the product of the following reaction. HSO, OH A. В. C. D.B and C E. None of the cho ices is correct.6. Provide the structure for the major product in the following reactions. b. P f. OH g. Lia * Oia ملی CI 1. SOCI₂, pyr. 2. to Br 2 1. LIAIH4 (xs) 2. H₂O 1. LIAI(OR) 3H 2. H₂O 2. NH₂ Et₂CuLi 1. EtMgBr (xs) 2. H₂O 1. Mg 2. CO₂ 3. H* 4. SOCI₂, pyr 1. [H], NaBH3CN, EtNH₂ CI pyridine
- Taking into account anti periplanar geometry, predict the major E2 product formed from each starting material. b. с. d. a. "CH CH3 ČH(CH3)2 ČH(CH3)23. Provide a synthetic route to the following compound(s) а. Br OH from H. D b. from SCH3a.) b.) LOCH 3 CHO Determine and draw the product of the following reactions. HNO3 / H₂SO4 HNO3 / H₂SO4 c.) ОНС d.) CH3 OCH3 CH3 OCH3 HNO3 / H₂SO4 HNO3/H₂SO4