4) Given the reaction and data below: 2 NOCL (g) → 2 NO(g) + Cl2 (g) [NOCI]o (molecules-cm-3) 3.00 x 1016 2.00 x 1016 1.00 x 1016 4.00 x 1016 Initial rate (mol-L-¹.s-¹) 5.98 x 104 2.66 x 104 6.64 x 103 1.06 x 105 a. Determine the rate law and value for the rate constant k, including units. b. What is the overall order of the reactions? c. What is the rate of appearance of Cl2 and the rate of disappearance of NOCI for experiment 1?

Chemistry for Engineering Students
4th Edition
ISBN:9781337398909
Author:Lawrence S. Brown, Tom Holme
Publisher:Lawrence S. Brown, Tom Holme
Chapter11: Chemical Kinetics
Section: Chapter Questions
Problem 11.35PAE: 11.35 For the reaction 2 NO(g) + 2 H?(g) — N,(g) + 2 H,O(g) at 1100°C, the following data have been...
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4) Given the reaction and data below:
[NOCI]o (molecules.cm-³)
3.00 x 1016
2.00 x 1016
1.00 x 1016
2 NOCI(g) 2 NO(g) + Cl₂ (g)
4.00 x 1016
a. m = 2, k = ~2 x 1013
b. 2
c. ~60000, -100000
Initial rate (mol-L-¹.s-¹)
5.98 x 104
2.66 x 104
6.64 x 103
1.06 x 105
Transcribed Image Text:4) Given the reaction and data below: [NOCI]o (molecules.cm-³) 3.00 x 1016 2.00 x 1016 1.00 x 1016 2 NOCI(g) 2 NO(g) + Cl₂ (g) 4.00 x 1016 a. m = 2, k = ~2 x 1013 b. 2 c. ~60000, -100000 Initial rate (mol-L-¹.s-¹) 5.98 x 104 2.66 x 104 6.64 x 103 1.06 x 105
4) Given the reaction and data below:
2 NOCL (g) → 2 NO(g) + Cl₂ (g)
[NOCI]o (molecules-cm-3)
3.00 x 1016
2.00 x 1016
1.00 x 1016
4.00 x 1016
Initial rate (mol-L-¹.s-¹)
5.98 x 104
2.66 x 104
6.64 x 103
1.06 x 105
a. Determine the rate law and value for the rate constant k, including
units.
b. What is the overall order of the reactions?
c. What is the rate of appearance of Cl2 and the rate of disappearance
of NOCI for experiment 1?
Transcribed Image Text:4) Given the reaction and data below: 2 NOCL (g) → 2 NO(g) + Cl₂ (g) [NOCI]o (molecules-cm-3) 3.00 x 1016 2.00 x 1016 1.00 x 1016 4.00 x 1016 Initial rate (mol-L-¹.s-¹) 5.98 x 104 2.66 x 104 6.64 x 103 1.06 x 105 a. Determine the rate law and value for the rate constant k, including units. b. What is the overall order of the reactions? c. What is the rate of appearance of Cl2 and the rate of disappearance of NOCI for experiment 1?
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