3) Venlafaxine is a Wyeth antidepressant that is synthesized on a commercial scale from the starting material shown. Suggest a plausible synthesis using the same starting material. MeO MeO H₂N. OH
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- 3) Venlafaxine is a Wyeth antidepressant that is synthesized on a commercial scale from the starting material shown. Suggest a plausible synthesis using the same starting material. CI MeO MeO H₂N OHWhat compound is the major product of the reaction sequence shown below? (1) KCN ethanol Он (A) NH2 (B) (2) LIAIH, (xS)/ether (3) dil. H* H;O он NH2 OH (C) (D) Compound C Compound D )Compound A O Compound BElectrostatic potential maps of anisole and thioanisole are shown. Which do you think is the stronger acid, p-methoxybenzoic acid or p-(methylthio)benzoic acid? Explain.
- Following is the structure of miconazole, the active antifungal agent in a number of over-the-counter preparations, including Monistat, that are used to treat vaginal yeast infections. One of the compounds needed for the synthesis of miconazole is the trichloro derivative of toluene shown on its right. (a) Show how this derivative can be synthesized from toluene. (b) How many stereoisomers are possible for miconazole?3. Propose a plausible mechanism for the following transformation: & Q & CF3 H₂N CN 'N CF HOHReaction of p-cresol with two equivalents of 2-methylprop-1-ene affordsBHT, a preservative with molecular formula C15H24O. BHT gives thefollowing 1H NMR spectral data: 1.4 (singlet, 18 H), 2.27 (singlet, 3 H), 5.0(singlet, 1 H), and 7.0 (singlet, 2 H) ppm. What is the structure of BHT?Draw a stepwise mechanism illustrating how it is formed.
- Identify the following compound from its IR and proton NMR spectra. C,H1,0: 'H NMR 8 3.31 (3H, s); 8 2.41 (1H, s); & 1.43 (6H, s) IR: 2110, 3300 cm-1 (sharp) Draw the compound.Atenolol is a beta blocker medication primarily used to treat high blood pressure and heart- associated chest pain. Other uses include the prevention of migraines and treatment of certain irregular heart beats It is taken by mouth or by injection into a vein. It can also be used with other blood pressure medications. OH .N. CH3 ČH3 H2N° suggest industrial synthetic approach towards synthesis of this drug (atenolol) and provide reasons and advantages of your proposed synthetic approach.2. Propose the synthesis of following compound: OH
- iv)Propose a mechanism (curved arrow formalism) for the reaction of the synthesis of a sulfonamide derivative from sulfathiazoleIbufenac, a para-disubstituted arene with the structureHO2CCH2C6H4CH2CH(CH3)2 , is a much more potent analgesic thanaspirin, but it was never sold commercially because it caused livertoxicity in some clinical trials. Devise a synthesis of ibufenac frombenzene and organic halides having fewer than five carbons.OH - NH, Br2/KOH →product; 1. (a-hydroxy amide) Product of this Hoffmann bromamide reaction is : OH (a) Ph – Ĉ-CH3 (Ъ) Ph — CHO (c) Ph- CH3 (d) Ph – CH2 -NH2 NO2