3) Given the following reaction: a) Draw the mechanism for the formation of two possible compounds, which are isomers. b) Illustrate what the methyl resonance(s) would look like in the proton spectrum of one isomer. c) Draw a mechanism for the reductive elimination from one of your two isomers. SMe2 N CH3-1 Pt CH3
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- Draw the reaction mechanism for the reaction between an aldehyde and water under acidic conditions. (H') H,01,3-Butadiene undergoes an electrophilic addition with HBr. Complete the steps in the mechanism to produce the product shown. 2) Draw both the organic and inorganic intermediate species. Include all nonbonding electrons and charges. Draw a curved arrow to convert the intermediate into the product shown. 1) Add curved arrows for the first step. -Br: H, :Br: Нзс -сн—CH2 нdraw a correct mechanism to react with 2-methylocta-4,6-dien-1-amine with the given reagent. Again, disregard any parts of the molecule represented by R-groups and focus on the given portion of the molecule. Be sure the correct mechanism arrives at the correct product of the reaction. The incorrect mechanism may or may not have the correct product
- 027 In Part 1 add the curved arrows to the nucleophilic acyl substitution reaction mechanism. In Part 2, answer the multiple-choice question about the reaction in Part 1. Part 1 4 See Periodic Table O See Hint :0: :Br: Add the missing curved arrow notation. S CI Br Part 2 Which statement is most correct regarding the equilibrium for the above reaction? Choose one: O The equilibrium favors the right (i.e., Kea > 1) because acetate is a better leaving group than bromide. O The equilibrium favors the right (i.e., Kea > 1) because bromide is a better leaving group than acetate. O The equilibrium favors the left (i.e., Keq« 1) because acetate is a better leaving group than bromide. O The equilibrium favors the left (i.e., Keg 1) because bromide is a better leaving group than acetate. +Identify the most acid proton on each molecule and explain your reasoning using ARIO. Pick a base that could deprotonate that proton, draw the mechanism (arrows) and products and estimate the pkas он HO. он OHCI5. Add all missing lone pairs in each compound and product. Determine the most acidic proton in the starting material - explain why it is the most acidic. Show a mechanism for the acid-base reaction. (a) OH
- Draw the most stable resonance form for the intermediate in the following electrophilic substitution reaction. CI CI HNO3 / H2SO4 O2N You do not have to consider stereochemistry. • Include all valence lone pairs in your answer. • In cases where there is more than one answer, just draw one.Draw the mechanism for the reaction of an alkyl halide with sodium azide followed by reduction. Complete the mechanism of the initial step of the reaction, then identify the key intermediate and the product. Step 1: Draw curved arrows. o z + Na + || : z: I Step 2: Complete the intermediate. Na +The following molecules are subject to substitution (SN1 or SN2) reaction conditions. a) Identify if the leaving group (-Br) is attached to a 3°, 2°, 1°, or methyl Carbon. b) Rank the molecule with respect to their SN1 reactivity, with 1 being the fastest and 4 being the slowest. c) Rank the molecule with respect to their SN2 reactivity, with 1 being the fastest and 4 being the slowest. Br Br CH3B Br a. type of Carbon on C-Br b. SN1 reactivity (1 fastest, 4 slowest) c. SN2 reactivity (1 fastest, 4 slowest)
- 7. Draw the mechanism for the reaction. There should be three steps: 1) protonation, 2) Nu attack, 3) proton removal. -ОН H* НоOrganic Chemistry Maxwell presented by Macmillan Learning Complete the curved arrow mechanism of the following double elimination reaction when 2,3-dibromopentane is treated with two equivalents of sodium amide and heated in mineral oil. a) Use three curved arrows to show the b) Use three curved arrows to show the elimination of the first hydrogen bromide. elimination of the second hydrogen bromide. Select Draw Rings More Erase Select Draw Rings More Erase H Br Br N : Br : : NH, : NH, : Br : : NH, Br: : Br: Q 2 QConsider the reduction of 4-nitrobenzaldehyde using sodium borohydride, NaBH4 in ethanol: what happen at initial step 1) a hydride ion attacks the carbonyl group's carbon atom 2)a hydride ion attacks the nitro group's nitrogen atom 3) a sodium ion attacks the carbonyl groups oxygen atom 4) a sodium ion attacks a nitro group's oxygem atom