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- GINE REASONABLE SYNTJE SËS OF THE INDICATED PeoDuCTS FROM THE GIVEN STARTING MATERIALS, Snow STERE OCHE M - ISTRY WHERE IT IS RELEVANT (*), AND SHOW ANY INTER - MEDIATES THAT COULD BE O THER REAGENTS You DEE M FIT, AS LONG A5 THHE-i MAKE CHEMICAL SENSE ARE STABLE ENOUGH TO EXIST, ISOLATED. You MAY usE ANí PhAs far back as the 16th century, South American Incas chewed the leaves of the coca bush, Erythroxylon coca, to combat fatigue. Chemical studies of Erythroxylon coca by Friedrich Wöhler in 1862 resulted in the discovery of cocaine, C17H21NO4, as the active component. Basic hydrolysis of cocaine leads to methanol, benzoic acid, and another compound called ecgonine, C9H15NO3. Oxidation of ecgonine with CrO3 yields a keto acid that readily loses CO2 on heating, giving tropinone. (a) What is a likely structure for the keto acid? (b) What is a likely structure for ecgonine, neglecting stereochemistry? (c) What is a likely structure for cocaine, neglecting stereochemistry?The diazotization of aniline first involves the formation of NO+ (nitrosonium ion) by the dehydration of nitrous acid with sulfuric acid. The aniline nitrogen then acts as a nucleophile and eventually loses water. Propose a mechanism for the formation of the dizaonium salt of aniline. Use curved arrows to show all electron movement.
- The following reactions are unlikely to provide the indicated product in high yield. What is wrong with each?please show Allariorw pusheng wedrunsir 24.34 Draw the product of each of the following reactions. 1. KMno, NAOH, s ? (a) (b) 1. KMno. NaOH, A ? (c) 1. Og, -78 °C 2. HO 2. HO ? 2. Zn. HOAC (d) (e) HO 1. OsO4. H,O2 -? 2. HIO, 1. O3. -78 C 2. H,O, KMNO4 NaOH, AWhich of the following reagents should be reacted with the reactant to get the given product? Select one: a. ethanamine; LIAIH, diethyl ether, H₂O Ob. NaOCH₂CH3; H₂in Pt OC. methanamine; NaBH, O d. methanol; DIBAL, H₂0* Br H to tr
- (weopentane) it consists of aminterantion na?twith magnesium with ather the product dissolved with waten? (Grignand regunt}Write the missing product or reagent in each of the following: En0; Eno CO₂Me OH I ?????? OTT 1) p Ts OH (cat.), Me OH CH₂Cl₂,rt. 2 h (98%yield) 2) 1) NaBH4 2) NH₂Cl(aq) 3) NaI0, Bu NBT (COCI), DMSO E₂N, -78°C ACO OAC I-OAC 0 LCHOProvide the missing reagent indicated by "???" CI ??? OH (+ other products)
- phenylfulvene Mo t Moleic to that 6. produce bub white broduct 10/our c0/0rless the of it has white nana e po duct gtoe explain 2710 but red. not ahe of this reactHon. assaProvide the mechanism for the following: A) Lou 1. BR, PBr; Br. 2. H,0º HO- 1 Cle, NaOH 2. H;0º B. ph I HO Bl2 C) ph Br会ll l 618527...5289_2 > By using reductive amination show how could prepare the following organic compound? Use all possible starting material 目