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- Show how to synthesize the following amines from the indicated starting materials byacylation–reduction. b) N-benzylaniline from anilinePropose a reaction for the formation of the following products involving esterformation.Synthesize the following product via acetoacetic ester synthesis. Use any necessary reagents.
- Synthesize the following product via acetoacetic ester synthesis. Use any necessary reagents. Show the mechanisms involved.Amobarbital is a sedative marketed under the trade name Amytal. Propose a synthesis of amobarbital, using diethyl malonate and urea as two of the starting materials.Phenyl 4-aminosalicylate is a drug used in the treatment of tuberculosis. Propose a synthetic route for this compound starting from 4-nitrosalicylic acid. The synthesis involves multiple steps. Specify all the reagents and the reaction conditions it may require in each step.
- The mechanism for acidic hydrolysis of a nitrile resembles the basic hydrolysis, exceptthat the nitrile is first protonated, activating it toward attack by a weak nucleophile (water).Under acidic conditions, the proton transfer (tautomerism) involves protonation on nitrogen followed by deprotonation on oxygen. Propose a mechanism for the acid-catalyzedhydrolysis of benzonitrile to benzamide.Propose a synthesis of the following molecule, starting with cyclohexanone and using any other reagents necessary:Amobarbital is a sedative marketed under the trade name Amytal. Propose a synthesis of amobarbital, using diethyl malonate and urea as two ofthe starting materials.
