11.An acid-base equilibrium system is created by dissolving 0.15 mol HNO2 inwater and diluting the resulting solution to a volume of 1.0 L. What is the effectof adding 0.020 mol NO2 (aq) to this solution? How will pH change (calculate pHbefore and after the addition. For HNO2 Ka = 4.5 x 104)? How willconcentrations of HNO2 and NO2 at equilibrium change?

Answered: 11.An acid-base equilibrium system is…

Chemistry

9th Edition

ISBN:9781133611097

Author:Steven S. Zumdahl

Publisher:Steven S. Zumdahl

Chapter15: Acid-base Equilibria

Section: Chapter Questions

Problem 7ALQ: You have a solution of the weak acid HA and add some HCl to it. What are the major species in the...

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You have a solution of the weak acid HA and add some of the salt NaA to it. What are the major species in the solution? What do you need to know to calculate the pH of the solution, and how would you use this information? How does the pH of the solution of just the HA compare with that of the final mixture? Explain.
You have a solution of the weak acid HA and add some HCl to it. What are the major species in the solution? What do you need to know to calculate the pH of the solution, and how would you use this information? How does the pH of the solution of just the HA compare with that of the final mixture? Explain.
. How is the strength of an acid related to the fact that a competition for protons exists in aqueous solution between water molecules and the anion of the acid?
Acrylic acid is used in the polymer industry in the production of acrylates. Its K, is 5.6 X 10“’. What is the pH of a 0.11 M solution of acrylic acid, CH2CHCOOH?
An aqueous solution of 0.057 M weak acid, HX, has a pH of 4.65. What is the pH of the solution if 0.018 mol of KX is dissolved in one liter of the weak acid?
Consider a 0.60-M solution of HC3H5O3, lactic acid (Ka = 1.4 104). a. Which of the following are major species in the solution? i. HC3H5O3 ii. C3H5O3 iii. H+ iv. H2O v. OH b. Complete the following ICE table in terms of x, the amount (mol/L) of lactic acid that dissociates to reach equilibrium. c. What is the equilibrium concentration for C3H3O3? d. Calculate the pH of the solution.
Kafor acetic acid (HC2H3O2) at 25°C is 1.754105 . At 50°C, Kais 1.633105 . Assuming that H° and S° are not affected by a change in temperature, calculate S° for the ionization of acetic acid.
Sketch the titration curve for a weak acid titrated by a strong base. When performing calculations concerning weak acidstrong base titrations, the general two-slep procedure is to solve a stoichiometry problem first, then to solve an equilibrium problem to determine the pH. What reaction takes place in the stoichiometry part of the problem? What is assumed about this reaction? At the various points in your titration curve, list the major species present after the strong base (NaOH, for example) reacts to completion with the weak acid, HA. What equilibrium problem would you solve at the various points in your titration curve to calculate the pH? Why is pH 7.0 at the equivalence point of a weak acid-strong base titration? Does the pH at the halfway point to equivalence have to be less than 7.0? What does the pH at the halfway point equal? Compare and contrast the titration curves for a strong acidstrong base titration and a weak acidstrong base titration.
8-55 We commonly refer to a buffer as consisting of approximately equal molar amounts of a weak acid and its conjugate base—for example, CH3COOH and CH3COO-. Is it also possible to have a buffer consisting of approximately equal molar amounts of a weak base and its conjugate acid? Explain.
Ka for acetic acid at 25.0C is 1754 105. At 55.0C, Ka is 1.625 105. What are H and S for the ionization of acetic acid?
Most naturally occurring acids are weak acids. Lactic acid is one example. CH3CH(OH)CO2H(s)+H2O(l)H3O+(aq)+CH3CH(OH)CO2(aq) If you place some lactic acid in water, it will ionize to a small extent, and an equilibrium will be established. Suggest some experiments to prow that this is a weak acid and that the establishment of equilibrium is a reversible process.
Amino acids are an important group of compounds. At low pH, both the carboxylic acid group (CO2H) and the amine group (NHR) are protonated. However, as the pH of the solution increases (say, by adding base), the carboxylic acid proton is removed, usually at a pH between 2 and 3. In a middle range of pHs, therefore, the amine group is protonated, but the carboxylic acid group has lost the proton. (This is called a zwitterion.) At more basic pH values, the amine proton is dissociated. What is the pH of a 0.20 M solution of alanine hydrochloride, [NH3CHCH3CO2H]Cl?

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