1. The mass spectrum of 3-hexanol is given below. 100 Intensity 55 80- 60- 40 40 20 20 59 73 3-Hexanol El MW = 102 OH 0 0 10 20 30 40 50 60 70 80 90 100 110 120 130 140 150 m/z (a) Rationalize the small size of the molecular ion peak at m/z 102. (b) Assign structures to all the labeled species and rationalize their formation.

The mass spectrum of compound B is shown below. 100 180 80 181 77 В 182 20 104 25 50 75 100 125 150 175 200 m/z (i) Identify the molecular ion peak of compound B. (ii) Explain the peak at m/z 182 in terms of intensity. (iii) Explain the formation of the other labelled fragments (m/z 180, 104 and 77). Relative Intensity

Mass spectroscopic.  What is the isotopic peak pattern of each : Organic compound with 2 bromine atoms. Organic compound with 2 chlorine atoms.

(a) Based on the mass spectrum shown below, 100 73 LOH 80 - A 58 20 - 100 10 20 30 40 50 60 70 80 90 100 110 m/z (i) identify the molecular ion peak of compound A. (ii) explain how the labelled fragments are formed. Relative Intensity

Account for the presence of the following peak  in the mass spectrum of hexanoic acid, CH3(CH2)4COOH. Q.) A series of peaks differing by 14 amu at m/z 45, 59, 73, and 87

Q.1. Predict the relative intensity of the M, M+1, and M+2 peaks for a low resolution mass spectrum of a compound with molecular formula, C6H13Br. The natural abundances of the select isotopes are given below. 35 Cl: 75.8% 79Br: 50.5% 12C: 98.89% 37Cl: 24.2% (The ratio is almost 3:1) 81Br: 49.5% (The ratio is almost 1:1) 13C: 1.11%

The low-resolution mass spectrum of an unknown analgesic X had a molecular ion of 151. Possible molecular formulas include C7H5NO3, C8H9NO2, and C10H17N. Highresolution mass spectrometry gave an exact mass of 151.0640. What is the molecular formula of X?

Identify the following in the given IR Mass spectrum. Compound 1 Mass Spectroscopy: Interpretation of peaks: Compound 1 Mass Spectroscopy: MASS SPECTRUM 100 80 60 40 20 0.0- 10 20 30 40 50 60 70 m/z Interpretation of peaks: Rel. Intensity

An unknown hydrocarbon has a molecular ion peak at m/z = 84, with a relative intensity of 31.3. The M + 1 peak has a relative intensity of 2.06, and the M + 2 peak has a relative intensity of 0.08. What is the molecular formula for this substance?

5. Use the mass spectrum to propose a molecular formula for the compound. Show your work. 100 80 60 (M)* m/z = 87 intensity = 35% 40 (M+1) m/z = 88 intensity = 2% 20 0.0 0.0 20 40 60 80 100 m/z Rel. Intensity